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- W3201403746 abstract "Helicene is a functional material with chirality caused by its characteristic helical geometry. The inversion of its helicity by external stimuli is a challenging task in the advanced control of the molecular chirality. This study fabricated a novel helical molecule, specifically a pentahelicene-analogue twisted aromatic hydrocarbon fused with a graphene nanoribbon, via on-surface synthesis using multiple precursors. Noncontact atomic force microscopy imaging with high spatial resolution confirmed the helicity of the reaction products. The helicity was geometrically converted by pushing a CO-terminated tip into the twisted framework, which is the first demonstration of helicity switching at the single-molecule scale." @default.
- W3201403746 created "2021-09-27" @default.
- W3201403746 creator A5038079017 @default.
- W3201403746 creator A5065386605 @default.
- W3201403746 creator A5066899163 @default.
- W3201403746 date "2021-01-01" @default.
- W3201403746 modified "2023-10-17" @default.
- W3201403746 title "Mechanically induced single-molecule helicity switching of graphene-nanoribbon-fused helicene on Au(111)" @default.
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- W3201403746 doi "https://doi.org/10.1039/d1sc03976h" @default.
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