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• W3201414384 abstract "Four-dimensional (4D) printing of stimuli-responsive materials with the ability to change their shapes or functions when subjected to external stimuli has garnered much interest due to their tremendous potential applications in various biomedical and engineering devices. Recently, 4D printing of electrically-conductive shape memory polymers (SMPs) have become increasingly attractive due to its prospects in the fields of biomedicine, soft robotics, flexible electronics etc. However, translation of these research into practical applications are often hindered by low electrical conductivity, as well as complicated programming and design. In this work, we report a facile approach to achieve highly conductive SMP-based 4D-printed devices. The SMP-based devices can be printed on a typical 3D digital light projection (DLP) or stereolithography (SLA) printer from photopolymer resins with the ability to tune the shape memory transition temperatures ranging from 20 °C to 50 °C. High electrical conductivity up to 2 × 106 S m−1 was achieved through electroless deposition of copper with high adhesion strength of up to 1.5 MPa. The incorporation of a metallic coating allowed for enhanced shape recovery due to enhanced surface thermal conductivity. An application of the technique to fabricate smart switches with the ability to monitor environmental temperature changes to be used in electrical safety devices was successfully demonstrated. The approach presented herein may be further explored and developed to capitalise on the stimuli-responsiveness and electrical conductivity of 4D-printed SMPs to find value in various engineering applications." @default.
• W3201414384 created "2021-09-27" @default.
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• W3201414384 date "2022-02-01" @default.
• W3201414384 modified "2023-10-17" @default.
• W3201414384 title "Synergistic combination of 4D printing and electroless metallic plating for the fabrication of a highly conductive electrical device" @default.
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• W3201414384 doi "https://doi.org/10.1016/j.cej.2021.132513" @default.
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