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- W3201480652 abstract "The luminescent coarse-, micro- and nanocrystalline europium(III) terephthalate tetrahydrate (Eu2bdc3·4H2O) metal-organic frameworks were synthesized by the ultrasound-assisted wet-chemical method. Electron micrographs show that the europium(III) terephthalate microparticles are 7 μm long leaf-like plates. According to the dynamic light scattering technique, the average size of the Eu2bdc3·4H2O nanoparticles is equal to about 8 ± 2 nm. Thereby, the reported Eu2bdc3·4H2O nanoparticles are the smallest nanosized rare-earth-based MOF crystals, to the best of our knowledge. The synthesized materials demonstrate red emission due to the 5D0–7FJ transitions of Eu3+ upon 250 nm excitation into 1ππ* state of the terephthalate ion. Size reduction results in broadened emission bands, an increase in the non-radiative rate constants and a decrease in both the quantum efficiency of the 5D0 level and Eu3+ and the luminescence quantum yields. Cu2+, Cr3+, and Fe3+ ions efficiently and selectively quench the luminescence of nanocrystalline europium(III) terephthalate, which makes it a prospective material for luminescent probes to monitor these ions in waste and drinking water." @default.
- W3201480652 created "2021-09-27" @default.
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- W3201480652 date "2021-09-20" @default.
- W3201480652 modified "2023-10-06" @default.
- W3201480652 title "Ultrasound-Assisted Synthesis of Luminescent Micro- and Nanocrystalline Eu-Based MOFs as Luminescent Probes for Heavy Metal Ions" @default.
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- W3201480652 doi "https://doi.org/10.3390/nano11092448" @default.
- W3201480652 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8468986" @default.
- W3201480652 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34578764" @default.
- W3201480652 hasPublicationYear "2021" @default.