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• W320153913 abstract "This chapter summarizes the different biosynthetic steps of isoprenoid ether lipid biosynthesis in archaea, describing the underlying enzymatic reactions that have been characterized. The evolution of this lipid biosynthesis apparatus in a variety of archaea is discussed. The effect of the environment on the nature of the lipids present in archaeal cell membranes is scrutinized in an attempt to link structure and function. Similar to other isoprenoids, archaeal lipid side chains are assembled from two universal precursors: isopentenyl diphosphate (IPP) and its isomer dimethylallyl diphosphate (DMAPP). In archaea, geranylgeranyl diphosphate (GGPP) synthase can elongate DMAPP to obtain both farnesyl diphosphate (FPP) and GGPP, the latter being the isoprenyl forming the side chains of C20-C20 diether lipids. However, similar to the studies on partially saturated side chains, there is little experimental evidence on when these structures are formed during the process of archaeal lipid biosynthesis. The detection of CDP-archaeol synthase and archaetidylserine synthase activities in Methanothermobacter thermautotrophicus suggests that the biochemical steps for the addition of polar head groups on archaeal lipid precursors, might proceed in a manner analogous to fatty acid biosynthesis in bacteria. High-performance liquid chromotography (HPLC), in combination with electrospray mass spectrometry (ES-MS) was used to characterize the membrane phospholipids and glycolipids of halophilic archaea and the cold-adapted methanogen M. burtonii." @default.
• W320153913 created "2016-06-24" @default.
• W320153913 creator A5050421565 @default.
• W320153913 date "2014-04-30" @default.
• W320153913 modified "2023-10-02" @default.
• W320153913 title "Lipids: Biosynthesis, Function, and Evolution" @default.
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• W320153913 doi "https://doi.org/10.1128/9781555815516.ch15" @default.
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