FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201639170> ?p ?o ?g. }

• W3201639170 endingPage "13163" @default.
• W3201639170 startingPage "13151" @default.
• W3201639170 abstract "Plasma catalysis is an emerging new technology for the electrification and downscaling of NH3 synthesis. Increasing attention is being paid to the optimization of plasma catalysis with respect to the plasma conditions, the catalyst material, and their mutual interaction. In this work we use microkinetic models to study how the total conversion process is impacted by the combination of different plasma conditions and transition metal catalysts. We study how plasma-generated radicals and vibrationally excited N2 (present in a dielectric barrier discharge plasma) interact with the catalyst and impact the NH3 turnover frequencies (TOFs). Both filamentary and uniform plasmas are studied, based on plasma chemistry models that provided plasma phase speciation and vibrational distribution functions. The Langmuir–Hinshelwood reaction rate coefficients (i.e., adsorption reactions and subsequent reactions among adsorbates) are determined using conventional scaling relations. An additional set of Eley–Rideal reactions (i.e., direct reactions of plasma radicals with adsorbates) was added and a sensitivity analysis on the assumed reaction rate coefficients was performed. We first show the impact of different vibrational distribution functions on the catalytic dissociation of N2 and subsequent production of NH3, and we gradually include more radical reactions, to illustrate the contribution of these species and their corresponding reaction pathways. Analysis over a large range of catalysts indicates that different transition metals (metals such as Rh, Ni, Pt, and Pd) optimize the NH3TOFs depending on the population of the vibrational levels of N2. At higher concentrations of plasma-generated radicals, the NH3 TOFs become less dependent on the catalyst material, due to radical adsorptions on the more noble catalysts and Eley–Rideal reactions on the less noble catalysts." @default.
• W3201639170 created "2021-09-27" @default.
• W3201639170 creator A5007740952 @default.
• W3201639170 creator A5042038815 @default.
• W3201639170 creator A5050558998 @default.
• W3201639170 creator A5061052548 @default.
• W3201639170 creator A5062009633 @default.
• W3201639170 creator A5073709587 @default.
• W3201639170 date "2021-09-21" @default.
• W3201639170 modified "2023-10-18" @default.
• W3201639170 title "Plasma Catalysis for Ammonia Synthesis: A Microkinetic Modeling Study on the Contributions of Eley–Rideal Reactions" @default.
• W3201639170 cites W1109119040 @default.
• W3201639170 cites W1708754953 @default.
• W3201639170 cites W2002432343 @default.
• W3201639170 cites W2034376552 @default.
• W3201639170 cites W2086263983 @default.
• W3201639170 cites W2119732183 @default.
• W3201639170 cites W2153357396 @default.
• W3201639170 cites W2591413258 @default.
• W3201639170 cites W2751738947 @default.
• W3201639170 cites W2768089236 @default.
• W3201639170 cites W2769255851 @default.
• W3201639170 cites W2803852160 @default.
• W3201639170 cites W2811155234 @default.
• W3201639170 cites W2889500773 @default.
• W3201639170 cites W2901631874 @default.
• W3201639170 cites W2912440347 @default.
• W3201639170 cites W2918208034 @default.
• W3201639170 cites W2929739531 @default.
• W3201639170 cites W2939640222 @default.
• W3201639170 cites W2945824492 @default.
• W3201639170 cites W2959949293 @default.
• W3201639170 cites W2976899193 @default.
• W3201639170 cites W2980739205 @default.
• W3201639170 cites W2982313739 @default.
• W3201639170 cites W3005579086 @default.
• W3201639170 cites W3010816427 @default.
• W3201639170 cites W3014770530 @default.
• W3201639170 cites W3028242135 @default.
• W3201639170 cites W3031428568 @default.
• W3201639170 cites W3044318436 @default.
• W3201639170 cites W3087948582 @default.
• W3201639170 cites W3108866557 @default.
• W3201639170 cites W3110025921 @default.
• W3201639170 cites W3201143440 @default.
• W3201639170 cites W4300006503 @default.
• W3201639170 doi "https://doi.org/10.1021/acssuschemeng.1c02713" @default.
• W3201639170 hasPublicationYear "2021" @default.
• W3201639170 type Work @default.
• W3201639170 sameAs 3201639170 @default.
• W3201639170 citedByCount "33" @default.
• W3201639170 countsByYear W32016391702021 @default.
• W3201639170 countsByYear W32016391702022 @default.
• W3201639170 countsByYear W32016391702023 @default.
• W3201639170 crossrefType "journal-article" @default.
• W3201639170 hasAuthorship W3201639170A5007740952 @default.
• W3201639170 hasAuthorship W3201639170A5042038815 @default.
• W3201639170 hasAuthorship W3201639170A5050558998 @default.
• W3201639170 hasAuthorship W3201639170A5061052548 @default.
• W3201639170 hasAuthorship W3201639170A5062009633 @default.
• W3201639170 hasAuthorship W3201639170A5073709587 @default.
• W3201639170 hasConcept C102931765 @default.
• W3201639170 hasConcept C121332964 @default.
• W3201639170 hasConcept C139066938 @default.
• W3201639170 hasConcept C147789679 @default.
• W3201639170 hasConcept C159467904 @default.
• W3201639170 hasConcept C161790260 @default.
• W3201639170 hasConcept C175113610 @default.
• W3201639170 hasConcept C17525397 @default.
• W3201639170 hasConcept C178790620 @default.
• W3201639170 hasConcept C179104552 @default.
• W3201639170 hasConcept C185592680 @default.
• W3201639170 hasConcept C62520636 @default.
• W3201639170 hasConcept C75473681 @default.
• W3201639170 hasConcept C82706917 @default.
• W3201639170 hasConcept C89448510 @default.
• W3201639170 hasConceptScore W3201639170C102931765 @default.
• W3201639170 hasConceptScore W3201639170C121332964 @default.
• W3201639170 hasConceptScore W3201639170C139066938 @default.
• W3201639170 hasConceptScore W3201639170C147789679 @default.
• W3201639170 hasConceptScore W3201639170C159467904 @default.
• W3201639170 hasConceptScore W3201639170C161790260 @default.
• W3201639170 hasConceptScore W3201639170C175113610 @default.
• W3201639170 hasConceptScore W3201639170C17525397 @default.
• W3201639170 hasConceptScore W3201639170C178790620 @default.
• W3201639170 hasConceptScore W3201639170C179104552 @default.
• W3201639170 hasConceptScore W3201639170C185592680 @default.
• W3201639170 hasConceptScore W3201639170C62520636 @default.
• W3201639170 hasConceptScore W3201639170C75473681 @default.
• W3201639170 hasConceptScore W3201639170C82706917 @default.
• W3201639170 hasConceptScore W3201639170C89448510 @default.
• W3201639170 hasFunder F4320327336 @default.
• W3201639170 hasFunder F4320337480 @default.
• W3201639170 hasFunder F4320338335 @default.
• W3201639170 hasIssue "39" @default.
• W3201639170 hasLocation W32016391701 @default.
• W3201639170 hasLocation W32016391702 @default.
• W3201639170 hasOpenAccess W3201639170 @default.

• next