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- W3201662540 abstract "Based on the results of physicochemical analysis, IR-spectroscopy, derivatographic analysis and differential scanning calorimetry, it was established that the interaction of cerium(III) carbonate with methanesulfonic acid yields cerium(III) methanesulfonate Се(SO3CH3)34H2O. Thermolysis of complex compound Се(SO3CH3)34H2O proceeds via a complex chemical mechanism and is completed at the temperature of 540–5500C producing nanocrystalline powders of cerium(IV) oxide having cubic structure with primary particle sizes of 20–30 nm, aggregate sizes of 50–200 nm and specific surface area of 62–68 m2 g–1. A probable mechanism of thermal decomposition of cerium(III) methanesulfonate is proposed, which depends on the temperature conditions of the thermal decomposition process. At low temperatures, the thermolysis of Се(SO3CH3)34H2O proceeds by the mechanism of surface oxidation with the formation of cerium oxide. At temperatures above 4500C, thermolysis is transformed into combustion with a significant heat effect and the formation of nanosized powders of cerium(IV) oxide of the corresponding morphological structure. It was found that the solutions of cerium(III) methanesulfonate show antiviral activity in vitro." @default.
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- W3201662540 date "2021-10-01" @default.
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- W3201662540 title "Preparation, properties and application of cerium(III) methanesulfonate" @default.
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- W3201662540 doi "https://doi.org/10.32434/0321-4095-2021-138-5-30-36" @default.
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