FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201698903> ?p ?o ?g. }

• W3201698903 abstract "Although zeolitic imidazolate frameworks (ZIFs) have bright prospects in wide fields like gas storage/separation, catalysis and medicine, etc., their large-scale applications are bottlenecked by the absence of their low-cost commercial production technique. Here, we report an unconventional method suitable for environmentally friendly and low-cost mass-production of ZIFs. In this method, taking the synthesis of ZIF-8 as an example, ZnO was used instead of Zn(NO 3 ) 2 in traditional solvent synthesis methods and CO 2 was introduced to dissolve ZnO in aqueous solution of 2-methylimidazole (HMeim) and form water soluble salt ([ZnMeim] + [MeimCOO] - ) at room temperature. Then, by removing CO 2 through heating or vacuuming, Meim-ions are produced and instantaneously assemble with [ZnMeim] + s to generate ZIF-8 without any by-product. Due to the absence of strong acid anions (such as NO 3 − and Cl − et al.) in solution, the washing of filter cake required in the conventional approaches could be omitted and the filtrate containing only water and HMeim could be reused completely. This method is really green as no waste gas or liquid generates because CO 2 and water could be recycled perfectly. It overcomes almost all bottlenecks occurred in commercial production of ZIF-8 when using traditional methods. A pilot plant was established for mass-production of ZIF-8 and hundreds kilograms of ZIF-8 was produced, which indicates that the new method is not only environmentally friendly but also low cost and commercial accessibility. It is expected that the new method would open an avenue for commercial applications of ZIFs. • A new CO 2 aided method for ZIFs synthesis was proposed. • The shell effect of initially formed ZIF-8 lattice covering the ZnO particles was solved. • The filtrate could be reused readily for the following synthesis of ZIF-8 which further reduced the synthesis cost. • The method is environmentally friendly without waste gas/liquid discharge. • Low-cost mass production of ZIF-8 can be achieved by using this method." @default.
• W3201698903 created "2021-10-11" @default.
• W3201698903 creator A5018120068 @default.
• W3201698903 creator A5028110910 @default.
• W3201698903 creator A5037509867 @default.
• W3201698903 creator A5052514777 @default.
• W3201698903 creator A5056166029 @default.
• W3201698903 creator A5058073103 @default.
• W3201698903 creator A5059122082 @default.
• W3201698903 creator A5075474462 @default.
• W3201698903 creator A5043909024 @default.
• W3201698903 date "2021-09-01" @default.
• W3201698903 modified "2023-10-17" @default.
• W3201698903 title "A purely green approach to low-cost mass production of zeolitic imidazolate frameworks" @default.
• W3201698903 cites W1462661479 @default.
• W3201698903 cites W1970952005 @default.
• W3201698903 cites W1975459909 @default.
• W3201698903 cites W1976122321 @default.
• W3201698903 cites W1980442236 @default.
• W3201698903 cites W1985596029 @default.
• W3201698903 cites W1995954610 @default.
• W3201698903 cites W2000776200 @default.
• W3201698903 cites W2001037711 @default.
• W3201698903 cites W2028182782 @default.
• W3201698903 cites W2035447129 @default.
• W3201698903 cites W2041201967 @default.
• W3201698903 cites W2072470803 @default.
• W3201698903 cites W2114784691 @default.
• W3201698903 cites W2114837043 @default.
• W3201698903 cites W2120072163 @default.
• W3201698903 cites W2139482086 @default.
• W3201698903 cites W2155567038 @default.
• W3201698903 cites W2156809331 @default.
• W3201698903 cites W2158212508 @default.
• W3201698903 cites W2159039115 @default.
• W3201698903 cites W2162876368 @default.
• W3201698903 cites W2168630788 @default.
• W3201698903 cites W2321316383 @default.
• W3201698903 cites W2570504957 @default.
• W3201698903 cites W2765446679 @default.
• W3201698903 cites W2774705710 @default.
• W3201698903 cites W2782004231 @default.
• W3201698903 cites W2784259290 @default.
• W3201698903 cites W2789426661 @default.
• W3201698903 cites W2890080368 @default.
• W3201698903 cites W2900201798 @default.
• W3201698903 cites W2914764270 @default.
• W3201698903 cites W2940931307 @default.
• W3201698903 cites W2963343082 @default.
• W3201698903 cites W3006289439 @default.
• W3201698903 cites W3010615498 @default.
• W3201698903 cites W3012188347 @default.
• W3201698903 cites W3017230570 @default.
• W3201698903 cites W3023560539 @default.
• W3201698903 cites W3090532671 @default.
• W3201698903 cites W3091308430 @default.
• W3201698903 cites W3096150522 @default.
• W3201698903 cites W3108668196 @default.
• W3201698903 cites W3129161414 @default.
• W3201698903 cites W860818211 @default.
• W3201698903 doi "https://doi.org/10.1016/j.gee.2021.09.003" @default.
• W3201698903 hasPublicationYear "2021" @default.
• W3201698903 type Work @default.
• W3201698903 sameAs 3201698903 @default.
• W3201698903 citedByCount "6" @default.
• W3201698903 countsByYear W32016989032022 @default.
• W3201698903 countsByYear W32016989032023 @default.
• W3201698903 crossrefType "journal-article" @default.
• W3201698903 hasAuthorship W3201698903A5018120068 @default.
• W3201698903 hasAuthorship W3201698903A5028110910 @default.
• W3201698903 hasAuthorship W3201698903A5037509867 @default.
• W3201698903 hasAuthorship W3201698903A5043909024 @default.
• W3201698903 hasAuthorship W3201698903A5052514777 @default.
• W3201698903 hasAuthorship W3201698903A5056166029 @default.
• W3201698903 hasAuthorship W3201698903A5058073103 @default.
• W3201698903 hasAuthorship W3201698903A5059122082 @default.
• W3201698903 hasAuthorship W3201698903A5075474462 @default.
• W3201698903 hasBestOaLocation W32016989031 @default.
• W3201698903 hasConcept C127413603 @default.
• W3201698903 hasConcept C139719470 @default.
• W3201698903 hasConcept C150394285 @default.
• W3201698903 hasConcept C161790260 @default.
• W3201698903 hasConcept C162324750 @default.
• W3201698903 hasConcept C171534860 @default.
• W3201698903 hasConcept C178790620 @default.
• W3201698903 hasConcept C179104552 @default.
• W3201698903 hasConcept C179366358 @default.
• W3201698903 hasConcept C184651966 @default.
• W3201698903 hasConcept C185592680 @default.
• W3201698903 hasConcept C18903297 @default.
• W3201698903 hasConcept C192562407 @default.
• W3201698903 hasConcept C21880701 @default.
• W3201698903 hasConcept C2778348673 @default.
• W3201698903 hasConcept C2780596747 @default.
• W3201698903 hasConcept C27983359 @default.
• W3201698903 hasConcept C2985847231 @default.
• W3201698903 hasConcept C42360764 @default.
• W3201698903 hasConcept C65024703 @default.
• W3201698903 hasConcept C78519656 @default.
• W3201698903 hasConcept C86803240 @default.

• next