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- W3201728790 abstract "Thermodynamic and kinetic control of a chemical process is the key to access desired products and states. Changes are made when desired product is not accessible; one may manipulate the reaction with additional reagents, catalysts and/or protecting groups. Here we report the use of carbon dioxide to direct reaction pathways in order to selectively afford desired products in high reaction rates while avoiding the formation of byproducts. The utility of CO<sub>2</sub>-mediated selective cyanohydrin synthesis was further showcased by broadening Kiliani-Fischer synthesis to offer an easy access to variety of polyols, cyanohydrins, linear alkylnitriles, by simply starting from alkyl- and arylaldehydes, KCN and atmospheric pressure of CO<sub>2</sub>." @default.
- W3201728790 created "2021-10-11" @default.
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- W3201728790 date "2020-07-15" @default.
- W3201728790 modified "2023-09-24" @default.
- W3201728790 title "CO2-Enabled Cyanohydrin Synthesis and Facile Homologation Reactions" @default.
- W3201728790 doi "https://doi.org/10.26434/chemrxiv.12652361.v1" @default.
- W3201728790 hasPublicationYear "2020" @default.
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