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- W3201804951 abstract "We disclose that the carbonates of 4-hydroxy-2-cyclopentenones can form π-allylpalladium-based 1,2-carbodipoles, which isomerize to interesting η2 -Pd0 -cyclopentadienone complexes. Compared with the labile parent cyclopentadienone, the HOMO energy of the related η2 -complex was significantly raised via the back-bonding of Pd0 as a π-Lewis base, rendering the uncoordinated C=C bond an electron-richer dienophile in inverse-electron-demand aza-Diels-Alder-type reactions with diverse 1-azadienes. The vinylogous (aza)Morita-Baylis-Hillman or cross Rauhut-Currier addition to (imine)carbonyls or activated alkenes, respectively, was also realized to afford chiral [4+2] or [2+2] cycloadducts, respectively, after trapping the re-generated π-allylpalladium species. New C1 -symmetric ligands from simple chiral sources were developed, exhibiting high stereoselectivity even with racemic substrates via an unusual dynamic kinetic resolution process. Besides, tropone could be similarly activated by a Pd0 complex." @default.
- W3201804951 created "2021-10-11" @default.
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- W3201804951 date "2021-11-16" @default.
- W3201804951 modified "2023-10-16" @default.
- W3201804951 title "π‐Lewis‐Base‐Catalyzed Asymmetric Vinylogous Umpolung Reactions of Cyclopentadienones and Tropone" @default.
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- W3201804951 doi "https://doi.org/10.1002/anie.202111708" @default.
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