FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201820590> ?p ?o ?g. }

• W3201820590 endingPage "122622" @default.
• W3201820590 startingPage "122622" @default.
• W3201820590 abstract "The lower high-temperature decomposition (HTD) temperature of ammonium perchlorate (AP) and more heat release of composite solid propellants (CSPs) put forward higher requirements on thermal catalysts. Herein, a new anhydrous energetic coordination compound [Cu(AT)4]Cl2 was well-designed and synthesized by coordination reaction of copper(II) and 5-amino-1H-tetrazole (AT), in which copper(II) catalytic active center has catalytic effect on reducing the HTD temperature of AP, and energetic AT can increase heat release. The structure of [Cu(AT)4]Cl2 was well determined by single crystal X-ray diffraction. The excellent thermal stability of [Cu(AT)4]Cl2 was verified by the results of thermogravimetric analysis and non-isothermal kinetics method. The catalytic activity of [Cu(AT)4]Cl2 for AP thermal decomposition was studied by the differential thermal analytical. The results indicated that the HTD peak of AP was significantly decreased by 60 ​K–495 ​K, and the activation energy of AP decreased by 57.5 ​kJ ​mol−1 to 163.37 ​kJ ​mol−1. The results of TGA-FTIR shows that the [Cu(AT)4]Cl2 will decompose and produce HCN gas before catalyzing AP, then the thermal decomposition products participated in the thermal decomposition of AP as an effective component of catalysis. The mechanical sensitivities and energetic characteristics of [Cu(AT)4]Cl2 was also studied by mechanical sensitometer, Calvet-type differential thermal conductivity calorimeter, and Kamlet-Jacbos equations. The results indicated that [Cu(AT)4]Cl2 has lower sensitivity than Trinitrotoluene and brilliant energetic characteristics. The [Cu(AT)4]Cl2 is expected to be one candidate additive in CSPs for catalytic thermal decomposition of AP." @default.
• W3201820590 created "2021-10-11" @default.
• W3201820590 creator A5014577134 @default.
• W3201820590 creator A5036807643 @default.
• W3201820590 creator A5039787974 @default.
• W3201820590 creator A5061763108 @default.
• W3201820590 creator A5073912741 @default.
• W3201820590 creator A5078015559 @default.
• W3201820590 creator A5080387091 @default.
• W3201820590 creator A5083913461 @default.
• W3201820590 date "2021-12-01" @default.
• W3201820590 modified "2023-10-01" @default.
• W3201820590 title "Novel energetic coordination compound [Cu(AT)4]Cl2 for catalytic thermal decomposition of ammonium perchlorate" @default.
• W3201820590 cites W2007009115 @default.
• W3201820590 cites W2023609191 @default.
• W3201820590 cites W2024230208 @default.
• W3201820590 cites W2064860814 @default.
• W3201820590 cites W2127760362 @default.
• W3201820590 cites W2134531883 @default.
• W3201820590 cites W2161373105 @default.
• W3201820590 cites W2169873967 @default.
• W3201820590 cites W2171728280 @default.
• W3201820590 cites W2309586467 @default.
• W3201820590 cites W2329658280 @default.
• W3201820590 cites W2509760397 @default.
• W3201820590 cites W2531484885 @default.
• W3201820590 cites W2553791089 @default.
• W3201820590 cites W2751957757 @default.
• W3201820590 cites W2781824033 @default.
• W3201820590 cites W2811254522 @default.
• W3201820590 cites W2891224928 @default.
• W3201820590 cites W2899099616 @default.
• W3201820590 cites W2902248698 @default.
• W3201820590 cites W2905484486 @default.
• W3201820590 cites W2930466330 @default.
• W3201820590 cites W2939393711 @default.
• W3201820590 cites W2946322166 @default.
• W3201820590 cites W2955486416 @default.
• W3201820590 cites W2968282345 @default.
• W3201820590 cites W2971953892 @default.
• W3201820590 cites W2972085638 @default.
• W3201820590 cites W3006167026 @default.
• W3201820590 cites W3016478018 @default.
• W3201820590 cites W3017015582 @default.
• W3201820590 cites W3033610062 @default.
• W3201820590 cites W3039277598 @default.
• W3201820590 cites W3044744600 @default.
• W3201820590 cites W3091433632 @default.
• W3201820590 cites W3106382081 @default.
• W3201820590 cites W3109391413 @default.
• W3201820590 cites W3127084036 @default.
• W3201820590 cites W3133348714 @default.
• W3201820590 doi "https://doi.org/10.1016/j.jssc.2021.122622" @default.
• W3201820590 hasPublicationYear "2021" @default.
• W3201820590 type Work @default.
• W3201820590 sameAs 3201820590 @default.
• W3201820590 citedByCount "9" @default.
• W3201820590 countsByYear W32018205902022 @default.
• W3201820590 countsByYear W32018205902023 @default.
• W3201820590 crossrefType "journal-article" @default.
• W3201820590 hasAuthorship W3201820590A5014577134 @default.
• W3201820590 hasAuthorship W3201820590A5036807643 @default.
• W3201820590 hasAuthorship W3201820590A5039787974 @default.
• W3201820590 hasAuthorship W3201820590A5061763108 @default.
• W3201820590 hasAuthorship W3201820590A5073912741 @default.
• W3201820590 hasAuthorship W3201820590A5078015559 @default.
• W3201820590 hasAuthorship W3201820590A5080387091 @default.
• W3201820590 hasAuthorship W3201820590A5083913461 @default.
• W3201820590 hasConcept C120665830 @default.
• W3201820590 hasConcept C121332964 @default.
• W3201820590 hasConcept C145148216 @default.
• W3201820590 hasConcept C147789679 @default.
• W3201820590 hasConcept C160434732 @default.
• W3201820590 hasConcept C161790260 @default.
• W3201820590 hasConcept C178790620 @default.
• W3201820590 hasConcept C179104552 @default.
• W3201820590 hasConcept C185592680 @default.
• W3201820590 hasConcept C207114421 @default.
• W3201820590 hasConcept C2776704483 @default.
• W3201820590 hasConcept C2780709120 @default.
• W3201820590 hasConcept C39519442 @default.
• W3201820590 hasConcept C544153396 @default.
• W3201820590 hasConcept C544778455 @default.
• W3201820590 hasConcept C59061564 @default.
• W3201820590 hasConcept C60100273 @default.
• W3201820590 hasConcept C68913812 @default.
• W3201820590 hasConcept C76804077 @default.
• W3201820590 hasConcept C95121573 @default.
• W3201820590 hasConcept C97355855 @default.
• W3201820590 hasConceptScore W3201820590C120665830 @default.
• W3201820590 hasConceptScore W3201820590C121332964 @default.
• W3201820590 hasConceptScore W3201820590C145148216 @default.
• W3201820590 hasConceptScore W3201820590C147789679 @default.
• W3201820590 hasConceptScore W3201820590C160434732 @default.
• W3201820590 hasConceptScore W3201820590C161790260 @default.
• W3201820590 hasConceptScore W3201820590C178790620 @default.
• W3201820590 hasConceptScore W3201820590C179104552 @default.
• W3201820590 hasConceptScore W3201820590C185592680 @default.

• next