Matches in SemOpenAlex for { <https://semopenalex.org/work/W3201932416> ?p ?o ?g. }
- W3201932416 abstract "Abstract Synthetic homogeneous system known to date performing methane to methanol conversion using O 2 as terminal oxidant is unique and based on copper complex with piperazine-based ligand (Cu 3 L in Fig. 1) in a medium of acetonitrile. Prior work have shown that in order to achieve catalytic turnover, hydrogen peroxide is needed to regenerate the active site. We show in this paper that reaction solvent based on organic nitrile decompose concurrently with methane activation and that in the absence of either acetonitrile, Cu complex or hydrogen peroxide, the catalytic turnover does not happen. We show in this manuscript that the direct methane oxidation to methanol might have been mediated by catalytic Radziszewski oxidation between acetonitrile and H 2 O 2 . Additionally we have discovered that in the absence of methane, peroxide mediated acetonitrile decomposition also makes methanol via a background reaction which was hitherto unknown." @default.
- W3201932416 created "2021-10-11" @default.
- W3201932416 creator A5005376816 @default.
- W3201932416 creator A5030445732 @default.
- W3201932416 creator A5031575603 @default.
- W3201932416 creator A5031768968 @default.
- W3201932416 creator A5053956468 @default.
- W3201932416 creator A5061023491 @default.
- W3201932416 creator A5070853822 @default.
- W3201932416 date "2021-09-28" @default.
- W3201932416 modified "2023-09-26" @default.
- W3201932416 title "Role of catalytic nitrile decomposition in tricopper complex mediated direct partial oxidation of methane to methanol" @default.
- W3201932416 cites W1159000317 @default.
- W3201932416 cites W1826083868 @default.
- W3201932416 cites W1969756809 @default.
- W3201932416 cites W1972671394 @default.
- W3201932416 cites W1978458801 @default.
- W3201932416 cites W1979618038 @default.
- W3201932416 cites W1979836054 @default.
- W3201932416 cites W1980833468 @default.
- W3201932416 cites W1983247968 @default.
- W3201932416 cites W1984184890 @default.
- W3201932416 cites W1984991672 @default.
- W3201932416 cites W1988182038 @default.
- W3201932416 cites W1997079500 @default.
- W3201932416 cites W1999607810 @default.
- W3201932416 cites W2033446111 @default.
- W3201932416 cites W2037555252 @default.
- W3201932416 cites W2039474117 @default.
- W3201932416 cites W2043116839 @default.
- W3201932416 cites W2046718857 @default.
- W3201932416 cites W2060153539 @default.
- W3201932416 cites W2066221947 @default.
- W3201932416 cites W2088003592 @default.
- W3201932416 cites W2089025736 @default.
- W3201932416 cites W2098318046 @default.
- W3201932416 cites W2131937263 @default.
- W3201932416 cites W2133636451 @default.
- W3201932416 cites W2140233125 @default.
- W3201932416 cites W2152616388 @default.
- W3201932416 cites W2159590209 @default.
- W3201932416 cites W2252439771 @default.
- W3201932416 cites W2301994743 @default.
- W3201932416 cites W2314505024 @default.
- W3201932416 cites W2316511368 @default.
- W3201932416 cites W2321015209 @default.
- W3201932416 cites W2432848579 @default.
- W3201932416 cites W2507236899 @default.
- W3201932416 cites W2558703285 @default.
- W3201932416 cites W2578282122 @default.
- W3201932416 cites W2611645040 @default.
- W3201932416 cites W2790725185 @default.
- W3201932416 cites W2954359141 @default.
- W3201932416 cites W3012031355 @default.
- W3201932416 doi "https://doi.org/10.1038/s41598-021-98721-2" @default.
- W3201932416 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8478979" @default.
- W3201932416 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34584179" @default.
- W3201932416 hasPublicationYear "2021" @default.
- W3201932416 type Work @default.
- W3201932416 sameAs 3201932416 @default.
- W3201932416 citedByCount "3" @default.
- W3201932416 countsByYear W32019324162022 @default.
- W3201932416 crossrefType "journal-article" @default.
- W3201932416 hasAuthorship W3201932416A5005376816 @default.
- W3201932416 hasAuthorship W3201932416A5030445732 @default.
- W3201932416 hasAuthorship W3201932416A5031575603 @default.
- W3201932416 hasAuthorship W3201932416A5031768968 @default.
- W3201932416 hasAuthorship W3201932416A5053956468 @default.
- W3201932416 hasAuthorship W3201932416A5061023491 @default.
- W3201932416 hasAuthorship W3201932416A5070853822 @default.
- W3201932416 hasBestOaLocation W32019324161 @default.
- W3201932416 hasConcept C104577883 @default.
- W3201932416 hasConcept C110686534 @default.
- W3201932416 hasConcept C124681953 @default.
- W3201932416 hasConcept C161790260 @default.
- W3201932416 hasConcept C178790620 @default.
- W3201932416 hasConcept C179104552 @default.
- W3201932416 hasConcept C185592680 @default.
- W3201932416 hasConcept C2777463227 @default.
- W3201932416 hasConcept C2779240715 @default.
- W3201932416 hasConcept C2779607525 @default.
- W3201932416 hasConcept C516920438 @default.
- W3201932416 hasConcept C533411734 @default.
- W3201932416 hasConcept C75473681 @default.
- W3201932416 hasConceptScore W3201932416C104577883 @default.
- W3201932416 hasConceptScore W3201932416C110686534 @default.
- W3201932416 hasConceptScore W3201932416C124681953 @default.
- W3201932416 hasConceptScore W3201932416C161790260 @default.
- W3201932416 hasConceptScore W3201932416C178790620 @default.
- W3201932416 hasConceptScore W3201932416C179104552 @default.
- W3201932416 hasConceptScore W3201932416C185592680 @default.
- W3201932416 hasConceptScore W3201932416C2777463227 @default.
- W3201932416 hasConceptScore W3201932416C2779240715 @default.
- W3201932416 hasConceptScore W3201932416C2779607525 @default.
- W3201932416 hasConceptScore W3201932416C516920438 @default.
- W3201932416 hasConceptScore W3201932416C533411734 @default.
- W3201932416 hasConceptScore W3201932416C75473681 @default.
- W3201932416 hasFunder F4320332434 @default.
- W3201932416 hasIssue "1" @default.
- W3201932416 hasLocation W32019324161 @default.