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- W3202002284 abstract "Inorganic material-incorporated cation exchange membranes (CEMs) with improved properties have drawn attention for reverse electrodialysis (RED). This paper deals with improving CEMs properties by incorporating silica–magnetite inorganic materials from natural resources. First, silica and magnetite were extracted from rice husk and iron sand, respectively. CEMs were prepared using the phase inversion method by incorporating various ratios. The results showed that both silica and magnetite were in micron size with yields of 76.6% and 59.2% wt., respectively. The CEMs containing magnetite materials showed higher ion exchange capacity (IEC) and ionic conductivity than PVC membranes. However, they had a greater swelling degree. The presence of silica reduced the swelling degree from 18.38% to 7.15% leading to membrane strengthening. A maximum IEC and conductivity of CEMs of 0.26 m eq /g and 0.524 S/cm were obtained for the membrane prepared with a SiO 2 /Fe 3 O 4 ratio of 0:4, respectively. However, considering all aspects, the addition of a SiO 2 /Fe 3 O 4 ratio of 1:3 was the most significant for increasing the fixed cation density and conductivity by 27.49% and 2815%, respectively, compared to other ratios. Thus, this SiO 2 /Fe 3 O 4 ratio (1:3) should be considered for practical implementation. Performance examination using RED confirmed that the PVC/SiO 2 /Fe 3 O 4 can be used as CEM for power generating and had comparable performance to commercial membrane." @default.
- W3202002284 created "2021-10-11" @default.
- W3202002284 creator A5071912072 @default.
- W3202002284 creator A5074735532 @default.
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- W3202002284 date "2021-11-01" @default.
- W3202002284 modified "2023-09-29" @default.
- W3202002284 title "Incorporating silica-magnetite synthesized from natural resources into the cation exchange membranes" @default.
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- W3202002284 doi "https://doi.org/10.1016/j.jmrt.2021.09.142" @default.
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