FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3202081429> ?p ?o ?g. }

• W3202081429 endingPage "16708" @default.
• W3202081429 startingPage "16697" @default.
• W3202081429 abstract "Two different classes of hairy self-suspended nanoparticles in the melt state, polymer-grafted nanoparticles (GNPs) and star polymers, are shown to display universal dynamic behavior across a broad range of parameter space. Linear viscoelastic measurements on well-characterized silica-poly(methyl acrylate) GNPs with a fixed core radius (Rcore) and grafting density (or number of arms f) but varying arm degree of polymerization (Narm) show two distinctly different regimes of response. The colloidal Regime I with a small Narm (large core volume fraction) is characterized by predominant low-frequency solidlike colloidal plateau and ultraslow relaxation, while the polymeric Regime II with a large Narm (small core volume fractions) has a response dominated by the starlike relaxation of partially interpenetrated arms. The transition between the two regimes is marked by a crossover where both polymeric and colloidal modes are discerned albeit without a distinct colloidal plateau. Similarly, polybutadiene multiarm stars also exhibit the colloidal response of Regime I at very large f and small Narm. The star arm retraction model and a simple scaling model of nanoparticle escape from the cage of neighbors by overcoming a hopping potential barrier due to their elastic deformation quantitatively describe the linear response of the polymeric and colloidal regimes, respectively, in all these cases. The dynamic behavior of hairy nanoparticles of different chemistry and molecular characteristics, investigated here and reported in the literature, can be mapped onto a universal dynamic diagram of f/[Rcore3/ν0)1/4] as a function of (Narmν0f)/(Rcore3), where ν0 is the monomeric volume. In this diagram, the two regimes are separated by a line where the hopping potential ΔUhop is equal to the thermal energy, kBT. ΔUhop can be expressed as a function of the overcrowding parameter x (i.e., the ratio of f to the maximum number of unperturbed chains with Narm that can fill the volume occupied by the polymeric corona); hence, this crossing is shown to occur when x = 1. For x > 1, we have colloidal Regime I with an overcrowded volume, stretched arms, and ΔUhop > kBT, while polymeric Regime II is linked to x < 1. This single-material parameter x can provide the needed design principle to tailor the dynamics of this class of soft materials across a wide range of applications from membranes for gas separation to energy storage." @default.
• W3202081429 created "2021-10-11" @default.
• W3202081429 creator A5015126725 @default.
• W3202081429 creator A5018026577 @default.
• W3202081429 creator A5024975049 @default.
• W3202081429 creator A5033735762 @default.
• W3202081429 creator A5040910382 @default.
• W3202081429 creator A5049853479 @default.
• W3202081429 creator A5061583678 @default.
• W3202081429 creator A5066825727 @default.
• W3202081429 creator A5088450032 @default.
• W3202081429 creator A5091751404 @default.
• W3202081429 date "2021-10-08" @default.
• W3202081429 modified "2023-10-13" @default.
• W3202081429 title "Universal Polymeric-to-Colloidal Transition in Melts of Hairy Nanoparticles" @default.
• W3202081429 cites W1914109153 @default.
• W3202081429 cites W1969284695 @default.
• W3202081429 cites W1974697977 @default.
• W3202081429 cites W1975956828 @default.
• W3202081429 cites W1977304763 @default.
• W3202081429 cites W1983143896 @default.
• W3202081429 cites W1984080259 @default.
• W3202081429 cites W1986691427 @default.
• W3202081429 cites W1986988059 @default.
• W3202081429 cites W1988089526 @default.
• W3202081429 cites W1990702849 @default.
• W3202081429 cites W1994527011 @default.
• W3202081429 cites W1994639424 @default.
• W3202081429 cites W1995364603 @default.
• W3202081429 cites W2000485513 @default.
• W3202081429 cites W2007215624 @default.
• W3202081429 cites W2010087734 @default.
• W3202081429 cites W2010849739 @default.
• W3202081429 cites W2012644941 @default.
• W3202081429 cites W2015420045 @default.
• W3202081429 cites W2018991785 @default.
• W3202081429 cites W2019429499 @default.
• W3202081429 cites W2025672520 @default.
• W3202081429 cites W2029846496 @default.
• W3202081429 cites W2030428776 @default.
• W3202081429 cites W2031659535 @default.
• W3202081429 cites W2042732071 @default.
• W3202081429 cites W2043492526 @default.
• W3202081429 cites W2047272857 @default.
• W3202081429 cites W204867520 @default.
• W3202081429 cites W2050005607 @default.
• W3202081429 cites W2051893661 @default.
• W3202081429 cites W2052971487 @default.
• W3202081429 cites W2054734271 @default.
• W3202081429 cites W2061197763 @default.
• W3202081429 cites W2062255172 @default.
• W3202081429 cites W2067304016 @default.
• W3202081429 cites W2071820653 @default.
• W3202081429 cites W2074394590 @default.
• W3202081429 cites W2075430727 @default.
• W3202081429 cites W2075619912 @default.
• W3202081429 cites W2082686215 @default.
• W3202081429 cites W2082751246 @default.
• W3202081429 cites W2084382908 @default.
• W3202081429 cites W2088001308 @default.
• W3202081429 cites W2090156745 @default.
• W3202081429 cites W2139724033 @default.
• W3202081429 cites W2156370397 @default.
• W3202081429 cites W2159664510 @default.
• W3202081429 cites W2241929953 @default.
• W3202081429 cites W2246238294 @default.
• W3202081429 cites W2249966839 @default.
• W3202081429 cites W2258658925 @default.
• W3202081429 cites W2312655162 @default.
• W3202081429 cites W2317308652 @default.
• W3202081429 cites W2324975076 @default.
• W3202081429 cites W2325806896 @default.
• W3202081429 cites W2327175543 @default.
• W3202081429 cites W2329112354 @default.
• W3202081429 cites W2430224017 @default.
• W3202081429 cites W2487163862 @default.
• W3202081429 cites W2611890986 @default.
• W3202081429 cites W2621243142 @default.
• W3202081429 cites W2755323378 @default.
• W3202081429 cites W2910095434 @default.
• W3202081429 cites W2952229992 @default.
• W3202081429 cites W2981719892 @default.
• W3202081429 cites W3009654997 @default.
• W3202081429 cites W3022294701 @default.
• W3202081429 cites W3094002587 @default.
• W3202081429 cites W3102303190 @default.
• W3202081429 cites W3102805490 @default.
• W3202081429 cites W3108703184 @default.
• W3202081429 cites W3111551769 @default.
• W3202081429 cites W3157438296 @default.
• W3202081429 cites W3165179743 @default.
• W3202081429 doi "https://doi.org/10.1021/acsnano.1c06672" @default.
• W3202081429 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34623796" @default.
• W3202081429 hasPublicationYear "2021" @default.
• W3202081429 type Work @default.
• W3202081429 sameAs 3202081429 @default.
• W3202081429 citedByCount "18" @default.
• W3202081429 countsByYear W32020814292022 @default.

• next