FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3202105648> ?p ?o ?g. }

• W3202105648 endingPage "17254" @default.
• W3202105648 startingPage "17240" @default.
• W3202105648 abstract "We present a mechanistic study on the formation of an active ligand layer over Pd(111), turning the catalytic surface highly active and selective in partial hydrogenation of an α,β-unsaturated aldehyde acrolein. Specifically, we investigate the chemical composition of a ligand layer consisting of allyl cyanide deposited on Pd(111) and its dynamic changes under the hydrogenation conditions. On pristine surface, allyl cyanide largely retains its chemical structure and forms a layer of molecular species with the CN bond oriented nearly parallel to the underlying metal. In the presence of hydrogen, the chemical composition of allyl cyanide strongly changes. At 100 K, allyl cyanide transforms to unsaturated imine species, containing the C=C and C=N double bonds. At increasing temperatures, these species undergo two competing reaction pathways. First, the C=C bond become hydrogenated and the stable N-butylimine species are produced. In the competing pathway, the unsaturated imine reacts with hydrogen to fully hydrogenate the imine group and produce butylamine. The latter species are unstable under the hydrogenation reaction conditions and desorb from the surface, while the N-butylimine adsorbates formed in the first reaction pathway remain adsorbed and act as an active ligand layer in selective hydrogenation of acrolein." @default.
• W3202105648 created "2021-10-11" @default.
• W3202105648 creator A5009247208 @default.
• W3202105648 creator A5020125776 @default.
• W3202105648 creator A5024876786 @default.
• W3202105648 creator A5056036587 @default.
• W3202105648 creator A5057749007 @default.
• W3202105648 creator A5084069145 @default.
• W3202105648 date "2021-10-27" @default.
• W3202105648 modified "2023-10-16" @default.
• W3202105648 title "Competing Reaction Pathways in Heterogeneously Catalyzed Hydrogenation of Allyl Cyanide: The Chemical Nature of Surface Species" @default.
• W3202105648 cites W1591049584 @default.
• W3202105648 cites W1768517216 @default.
• W3202105648 cites W1963534188 @default.
• W3202105648 cites W1971654638 @default.
• W3202105648 cites W1975378251 @default.
• W3202105648 cites W1977486429 @default.
• W3202105648 cites W1980884420 @default.
• W3202105648 cites W1981023232 @default.
• W3202105648 cites W1982180016 @default.
• W3202105648 cites W1982830187 @default.
• W3202105648 cites W1983669046 @default.
• W3202105648 cites W1986052731 @default.
• W3202105648 cites W1989110919 @default.
• W3202105648 cites W1989319419 @default.
• W3202105648 cites W1994448876 @default.
• W3202105648 cites W1995514769 @default.
• W3202105648 cites W2001152310 @default.
• W3202105648 cites W2005619234 @default.
• W3202105648 cites W2010154632 @default.
• W3202105648 cites W2015624811 @default.
• W3202105648 cites W2016448331 @default.
• W3202105648 cites W2019326507 @default.
• W3202105648 cites W2019383751 @default.
• W3202105648 cites W2031346965 @default.
• W3202105648 cites W2034749870 @default.
• W3202105648 cites W2039329331 @default.
• W3202105648 cites W2053360557 @default.
• W3202105648 cites W2054272328 @default.
• W3202105648 cites W2074492684 @default.
• W3202105648 cites W2081991841 @default.
• W3202105648 cites W2082890370 @default.
• W3202105648 cites W2082956084 @default.
• W3202105648 cites W2084337547 @default.
• W3202105648 cites W2093368408 @default.
• W3202105648 cites W2146358314 @default.
• W3202105648 cites W2321660234 @default.
• W3202105648 cites W2328006743 @default.
• W3202105648 cites W2341689641 @default.
• W3202105648 cites W2350467316 @default.
• W3202105648 cites W2510465631 @default.
• W3202105648 cites W2517650931 @default.
• W3202105648 cites W2519886984 @default.
• W3202105648 cites W2606765686 @default.
• W3202105648 cites W2609217018 @default.
• W3202105648 cites W2610541099 @default.
• W3202105648 cites W2673388689 @default.
• W3202105648 cites W2730432668 @default.
• W3202105648 cites W2736780366 @default.
• W3202105648 cites W2753023124 @default.
• W3202105648 cites W2886407173 @default.
• W3202105648 cites W2896596367 @default.
• W3202105648 cites W2945811828 @default.
• W3202105648 cites W2950210422 @default.
• W3202105648 cites W2955299562 @default.
• W3202105648 cites W2972175690 @default.
• W3202105648 cites W2987192712 @default.
• W3202105648 cites W3033558127 @default.
• W3202105648 cites W3039425012 @default.
• W3202105648 cites W3160713191 @default.
• W3202105648 cites W3202105648 @default.
• W3202105648 cites W1541408528 @default.
• W3202105648 doi "https://doi.org/10.1002/chem.202103238" @default.
• W3202105648 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34608688" @default.
• W3202105648 hasPublicationYear "2021" @default.
• W3202105648 type Work @default.
• W3202105648 sameAs 3202105648 @default.
• W3202105648 citedByCount "4" @default.
• W3202105648 countsByYear W32021056482021 @default.
• W3202105648 countsByYear W32021056482022 @default.
• W3202105648 crossrefType "journal-article" @default.
• W3202105648 hasAuthorship W3202105648A5009247208 @default.
• W3202105648 hasAuthorship W3202105648A5020125776 @default.
• W3202105648 hasAuthorship W3202105648A5024876786 @default.
• W3202105648 hasAuthorship W3202105648A5056036587 @default.
• W3202105648 hasAuthorship W3202105648A5057749007 @default.
• W3202105648 hasAuthorship W3202105648A5084069145 @default.
• W3202105648 hasBestOaLocation W32021056482 @default.
• W3202105648 hasConcept C112887158 @default.
• W3202105648 hasConcept C116569031 @default.
• W3202105648 hasConcept C161790260 @default.
• W3202105648 hasConcept C170493617 @default.
• W3202105648 hasConcept C178213299 @default.
• W3202105648 hasConcept C178790620 @default.
• W3202105648 hasConcept C185592680 @default.
• W3202105648 hasConcept C2776573223 @default.
• W3202105648 hasConcept C2778455166 @default.
• W3202105648 hasConcept C2779825165 @default.

• next