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- W3202247832 abstract "While migratory functionalization of alkynes has been recognized as a unique way to access allylic functionalities via π-allyl metal intermediates, hydrofunctionalization of 2-alkynes to afford α-functional olefins has been unexplored. We describe herein the use of a cobalt hydride based system for regioselective migratory hydrofunctionalization of 2-alkynes to furnish α-vinylsilanes and α-vinylgermanes by a mechanistic understanding of the cobalt hydride species on alkyne π-bond migration. The key mechanism of alkyne π-bond migration by [bis(dicyclohexylphosphino)ethane]cobalt hydride is strongly supported by both experimental and computational studies, and the role of each reaction component, such as alkynes and silanes, is elucidated to rationalize the unique α-vinyl selectivity." @default.
- W3202247832 created "2021-10-11" @default.
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- W3202247832 date "2021-10-05" @default.
- W3202247832 modified "2023-10-15" @default.
- W3202247832 title "Regioselective Access to α-Vinylsilanes and α-Vinylgermanes by Cobalt-Catalyzed Migratory Hydrofunctionalization of 2-Alkynes" @default.
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- W3202247832 doi "https://doi.org/10.1021/acscatal.1c03769" @default.
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