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- W3202364496 endingPage "48699" @default.
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- W3202364496 abstract "The lithium (Li)-metal anode is deemed as the holy gray of the next-generation Li-metal system because of its high theoretical specific capacity, minimal energy density, and lowest standard electrode potential. Nevertheless, its commercial application has been limited by the large volume variation during charge and discharge, the unstable interface between the Li metal and electrolyte, and uneven deposition of Li. Herein, we present a 3D host (Cu) with lithiophilic matrix (CuO and SnO2) in situ modification via a facile ammonia oxidation method to serve as a current collector for the Li-metal anode. The 3D Cu host embellished by CuO and SnO2 is abbreviated as 3D CSCC. By increasing interfacial activity, lowering the nucleation barrier, and accommodating changes in volume of the Li metal, the 3D CSCC electrode effectively demonstrates a homogeneous and dendrite-free deposition morphology with an excellent cycling performance up to 3000 h at a 1.0 mA cm-2 current density. Additionally, the full cells paired with Li@3D CSCC anodes and LiCoO2 cathodes show good capacity retention performance at 0.2 C." @default.
- W3202364496 created "2021-10-11" @default.
- W3202364496 creator A5009562280 @default.
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- W3202364496 date "2021-10-07" @default.
- W3202364496 modified "2023-10-03" @default.
- W3202364496 title "Uniform Deposition of Li-Metal Anodes Guided by 3D Current Collectors with In Situ Modification of the Lithiophilic Matrix" @default.
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- W3202364496 doi "https://doi.org/10.1021/acsami.1c13896" @default.
- W3202364496 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34617438" @default.
- W3202364496 hasPublicationYear "2021" @default.
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