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• W3202372877 abstract "The hydrogenation behavior of Ti x Fe 2-x +4 wt% Zr alloys, x = 1.1, 1.15 and 1.2 has been investigated. All compositions presented a multiphase microstructure with a TiFe-matrix along with a secondary Ti 2 Fe-like phase and a Ti-rich BCC phase. The phase fraction varied with “x”. The increase of titanium abundance makes the alloy more stable, but this comes with a loss of hydrogen capacity. The formation of stable hydrides (Ti 2 FeH x and FCC) by the secondary phases is reported. The full capacity according to the Rietveld refinement data is calculated. The contribution of each phase matches well with the reversible capacity measured experimentally. The results shown and discussed give insight into the hydrogenation properties of the secondary phases and their effect on a TiFe-based alloy. • All samples presented good activation kinetics at RT and 20 bar of hydrogen. • The stability of the alloy increases with x however reversible capacity is reduced. • Ti 2 Fe-like phase forms a stable hydride with a calculated H/M between 4 and 3." @default.
• W3202372877 created "2021-10-11" @default.
• W3202372877 creator A5072493213 @default.
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• W3202372877 date "2021-11-01" @default.
• W3202372877 modified "2023-09-26" @default.
• W3202372877 title "Hydrogenation of TixFe2-x-based alloys with overstoichiometric Ti ratio (x = 1.1, 1.15 and 1.2)" @default.
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• W3202372877 doi "https://doi.org/10.1016/j.ijhydene.2021.09.077" @default.
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