Matches in SemOpenAlex for { <https://semopenalex.org/work/W3202521127> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W3202521127 abstract "The separation of trivalent transplutonium actinides from fission product lanthanide ions represents a challenging aspect of advanced nuclear fuel partitioning schemes. The challenge of this separation could be amplified in the context of the AFCI-UREX+1a process, as Np and Pu will accompany the minor actinides to this stage of separation. At present, the baseline lanthanide-actinide separation method is the TALSPEAK (Trivalent Actinide - Lanthanide Separation by Phosphorus reagent Extraction from Aqueous complexes) process. TALSPEAK was developed in the late 1960's at Oak Ridge National Laboratory and has been demonstrated at pilot scale. This process relies on the complex interaction between an organic and an aqueous phase both containing complexants for selectively separating the trivalent actinide. The 3 complexing components are: the di(2-ethylhexyl) phosphoric acid (HDEHP), the lactic acid (HL) and the diethylenetriamine-N,N,N',N'',N''-pentaacetic acid (DTPA). In this report we discuss observations on kinetic and thermodynamic features described in the prior literature and describe some results of our ongoing research on basic chemical features of this system. The information presented indicates that the lactic acid buffer participates in the net operation of the TALSPEAK process in a manner that is not explained by existing information on the thermodynamic features if the known Eu(III)-lactate species. (authors)" @default.
- W3202521127 created "2021-10-11" @default.
- W3202521127 creator A5002538355 @default.
- W3202521127 creator A5087805905 @default.
- W3202521127 date "2008-07-01" @default.
- W3202521127 modified "2023-09-26" @default.
- W3202521127 title "TALSPEAK Chemistry in Advanced Nuclear Fuel Cycles" @default.
- W3202521127 hasPublicationYear "2008" @default.
- W3202521127 type Work @default.
- W3202521127 sameAs 3202521127 @default.
- W3202521127 citedByCount "0" @default.
- W3202521127 crossrefType "journal-article" @default.
- W3202521127 hasAuthorship W3202521127A5002538355 @default.
- W3202521127 hasAuthorship W3202521127A5087805905 @default.
- W3202521127 hasConcept C103522932 @default.
- W3202521127 hasConcept C113411277 @default.
- W3202521127 hasConcept C117760992 @default.
- W3202521127 hasConcept C135788738 @default.
- W3202521127 hasConcept C145148216 @default.
- W3202521127 hasConcept C147789679 @default.
- W3202521127 hasConcept C151730666 @default.
- W3202521127 hasConcept C177322064 @default.
- W3202521127 hasConcept C178790620 @default.
- W3202521127 hasConcept C179104552 @default.
- W3202521127 hasConcept C184651966 @default.
- W3202521127 hasConcept C185592680 @default.
- W3202521127 hasConcept C191897082 @default.
- W3202521127 hasConcept C192562407 @default.
- W3202521127 hasConcept C197404232 @default.
- W3202521127 hasConcept C201770740 @default.
- W3202521127 hasConcept C2776622989 @default.
- W3202521127 hasConcept C2779343474 @default.
- W3202521127 hasConcept C2779781515 @default.
- W3202521127 hasConcept C2779931791 @default.
- W3202521127 hasConcept C2780232233 @default.
- W3202521127 hasConcept C40875361 @default.
- W3202521127 hasConcept C43617362 @default.
- W3202521127 hasConcept C4725764 @default.
- W3202521127 hasConcept C552554468 @default.
- W3202521127 hasConcept C555352317 @default.
- W3202521127 hasConcept C555451288 @default.
- W3202521127 hasConcept C86803240 @default.
- W3202521127 hasConceptScore W3202521127C103522932 @default.
- W3202521127 hasConceptScore W3202521127C113411277 @default.
- W3202521127 hasConceptScore W3202521127C117760992 @default.
- W3202521127 hasConceptScore W3202521127C135788738 @default.
- W3202521127 hasConceptScore W3202521127C145148216 @default.
- W3202521127 hasConceptScore W3202521127C147789679 @default.
- W3202521127 hasConceptScore W3202521127C151730666 @default.
- W3202521127 hasConceptScore W3202521127C177322064 @default.
- W3202521127 hasConceptScore W3202521127C178790620 @default.
- W3202521127 hasConceptScore W3202521127C179104552 @default.
- W3202521127 hasConceptScore W3202521127C184651966 @default.
- W3202521127 hasConceptScore W3202521127C185592680 @default.
- W3202521127 hasConceptScore W3202521127C191897082 @default.
- W3202521127 hasConceptScore W3202521127C192562407 @default.
- W3202521127 hasConceptScore W3202521127C197404232 @default.
- W3202521127 hasConceptScore W3202521127C201770740 @default.
- W3202521127 hasConceptScore W3202521127C2776622989 @default.
- W3202521127 hasConceptScore W3202521127C2779343474 @default.
- W3202521127 hasConceptScore W3202521127C2779781515 @default.
- W3202521127 hasConceptScore W3202521127C2779931791 @default.
- W3202521127 hasConceptScore W3202521127C2780232233 @default.
- W3202521127 hasConceptScore W3202521127C40875361 @default.
- W3202521127 hasConceptScore W3202521127C43617362 @default.
- W3202521127 hasConceptScore W3202521127C4725764 @default.
- W3202521127 hasConceptScore W3202521127C552554468 @default.
- W3202521127 hasConceptScore W3202521127C555352317 @default.
- W3202521127 hasConceptScore W3202521127C555451288 @default.
- W3202521127 hasConceptScore W3202521127C86803240 @default.
- W3202521127 hasLocation W32025211271 @default.
- W3202521127 hasOpenAccess W3202521127 @default.
- W3202521127 hasPrimaryLocation W32025211271 @default.
- W3202521127 hasRelatedWork W126706419 @default.
- W3202521127 hasRelatedWork W137645007 @default.
- W3202521127 hasRelatedWork W1508191818 @default.
- W3202521127 hasRelatedWork W1548361966 @default.
- W3202521127 hasRelatedWork W1577027278 @default.
- W3202521127 hasRelatedWork W1911257858 @default.
- W3202521127 hasRelatedWork W2012703647 @default.
- W3202521127 hasRelatedWork W2055248171 @default.
- W3202521127 hasRelatedWork W2332118732 @default.
- W3202521127 hasRelatedWork W2403522507 @default.
- W3202521127 hasRelatedWork W2611524797 @default.
- W3202521127 hasRelatedWork W2748033681 @default.
- W3202521127 hasRelatedWork W2916096875 @default.
- W3202521127 hasRelatedWork W320796532 @default.
- W3202521127 hasRelatedWork W592024389 @default.
- W3202521127 hasRelatedWork W615956 @default.
- W3202521127 hasRelatedWork W2769363878 @default.
- W3202521127 hasRelatedWork W2833393806 @default.
- W3202521127 hasRelatedWork W2957282656 @default.
- W3202521127 hasRelatedWork W2966443136 @default.
- W3202521127 isParatext "false" @default.
- W3202521127 isRetracted "false" @default.
- W3202521127 magId "3202521127" @default.
- W3202521127 workType "article" @default.