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- W3202675611 abstract "The first part involves the synthesized compounds from Cytosine derivatives [HE1, HE3, HE6, HE13] that were prepared by four reactions. The first line is the preparation of Mannich derivative by substitution on the (C–H) site of the most acidic (H) of Cytosine to synthesis the compound [HE1] by reacting Cytosine with Ethylamine and formaldehyde. Then, Schiff base was prepared by substitution on the (NH2) site of compound [HE1] by reacting [HE1] with 4Chlorobenzaldehyde to synthesis the compound [HE3]. Subsequently, Acetylene derivative was prepared by substitution on the (NH) site of compound [HE3] with Propargylbromide to synthesis the compound [HE6]. Afterwards, Mannich base was produced by substitution on the (C–H) site of the most acidic (H) of [HE6] with Dibenzylamine and Formaldehyde to synthesis the compound [HE13]. All these four reactions used the classical method. All reactions were monitored by using Thin Layer Chromatography (TLC). Make sure of some of the prepared compounds by FT-IR and some by H'-NMR and C13-NMR. In the second part an Acetylene derivative [HE6] was selected and it's interaction with CT-DNA was studied by observing the effect of binding on CTDNA structure, nitrogen bases and phosphate groups by using FT-IR and UVVisible techniques. The calculations were done by using experimental methods. The derivative binding with CT-DNA from groove minor sides, was concluded from studying FT-IR spectrum." @default.
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- W3202675611 date "2022-01-01" @default.
- W3202675611 modified "2023-09-26" @default.
- W3202675611 title "Synthesis and identification of new cytosine-derived compounds and study their binding with DNA" @default.
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- W3202675611 doi "https://doi.org/10.1016/j.matpr.2021.08.336" @default.
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