Matches in SemOpenAlex for { <https://semopenalex.org/work/W3202686075> ?p ?o ?g. }
- W3202686075 endingPage "1814" @default.
- W3202686075 startingPage "1805" @default.
- W3202686075 abstract "Conventional π-conjugated luminophores suffer from problems such as emission quenching, biotoxicity, environmental pollution, etc. The emerging nonconjugated and nonaromatic clusteroluminogens (CLgens) are expected to overcome these stubborn drawbacks, so research of CLgens shows great significance not only for practical application but also for the construction of fundamental photophysical theories. This perspective summarizes the unusual features of CLgens in comparison to traditional chromophores, such as nonconjugated molecular structures, unmatched absorption and excitation, excitation-dependent luminescence, multiple emission peaks, and room-temperature phosphorescence. Different from the theory of through-bond conjugation in π-conjugated luminophores, through-space interactions, including through-space n···n interaction and through-space n···π interaction, are regarded as the emitting sources of nonconjugated CLgens. In addition, the formation of network clusters is proposed as an efficient strategy to improve the performance of CLgens, and their potential applications of anticounterfeiting, photoelectronic devices, and bioimaging are prospected." @default.
- W3202686075 created "2021-10-11" @default.
- W3202686075 creator A5036979531 @default.
- W3202686075 creator A5073822569 @default.
- W3202686075 date "2021-09-30" @default.
- W3202686075 modified "2023-10-14" @default.
- W3202686075 title "Through-Space Interactions in Clusteroluminescence" @default.
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- W3202686075 doi "https://doi.org/10.1021/jacsau.1c00311" @default.