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- W3202788130 abstract "Three hypotheses are proposed to simplify calculations of chemical bond lengths and strengths, and these are exemplified through Group 1 molecules. The first is that if transient uncertainty effects are eliminated statistically, then causal wave functions in which each force component is assigned a corresponding guidance wave component with quantized abbreviated action are formed that are equivalent to the guidance waves proposed by de Broglie. The second hypothesis is that the wave corresponding to valence electron ‘exchange’ undergoes the wave property of reflection, and as wave impedances vary with orbital size, a size miss-match reduces the amount of exchange and shortens the bond. The third hypothesis is that the wave functions for heavy atoms have fewer nodes than the corresponding hydrogen excited states, in which case a new quantum effect is predicted. A set of Pythagorean-type relationships arise, and the resultant calculations are essentially of the pencil and paper difficulty. Bond lengths are readily calculated and the bond lengths of hydrides show excellent agreement with the proposed bond shortening expression. Calculated bond energies are in good agreement with observed values, except for the bond energies of the heavier hydrides. There are varying possible interpretations for given equations, and if the third hypothesis is not accepted, the proposed new quantum effect could be a short-cut means of ensuring compliance with the relation between displacement field and charge density as required by Maxwell’s equations." @default.
- W3202788130 created "2021-10-11" @default.
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- W3202788130 date "2002-09-01" @default.
- W3202788130 modified "2023-09-25" @default.
- W3202788130 title "The Calculation of Molecular Properties Through Guidance Waves. Part 2: Group I Elements" @default.
- W3202788130 hasPublicationYear "2002" @default.
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