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• W3202940919 abstract "At the air-ice interface, some aromatic compounds such as benzene and anthracene are surprisingly unreactive toward OH. This may be a consequence of the poor solvation of these compounds at the interface, resulting in clustering there. We test this hypothesis by comparing the reaction of OH with pyrene, a 4-ring polyaromatic hydrocarbon (PAH), to reactions of OH with the more water-soluble compounds coumarin and 7-hydroxycoumarin (7OHC). We observe that OH reacts readily with coumarin and 7OHC at both liquid and frozen air-water interfaces. Pyrene, a much less soluble compound, reacts with OH at the liquid surface but not at the air-ice interface. We report evidence of pyrene aggregation at the ice surface based on its broadened and red-shifted emission spectrum alongside fluorescence mapping of anthracene, a closely related 3-ring PAH, which shows bunching at the ice surface. By contrast, fluorescence mapping shows that coumarin is fairly homogeneously distributed at the air-ice interface. Together, these results suggest that the limited reactivity of some compounds toward OH at the ice surface may be a consequence of their propensity to self-aggregate, demonstrating that chemical morphology can play an important role in reactions at the ice surface." @default.
• W3202940919 created "2021-10-11" @default.
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• W3202940919 date "2021-10-01" @default.
• W3202940919 modified "2023-10-16" @default.
• W3202940919 title "Chemical Morphology Controls Reactivity of OH Radicals at the Air–Ice Interface" @default.
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• W3202940919 doi "https://doi.org/10.1021/acs.jpca.1c06434" @default.
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• W3202940919 hasPublicationYear "2021" @default.
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