FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3202956075> ?p ?o ?g. }

• W3202956075 endingPage "6020" @default.
• W3202956075 startingPage "6020" @default.
• W3202956075 abstract "Here we present the synthesis, structure and magnetic properties of complexes of general formula (Mn)(Me2NH2)4][Mn3(μ-L)6(H2O)6] and (Me2NH2)6[M3(μ-L)6(H2O)6] (M = CoII, NiII and CuII); L-2 = 4-(1,2,4-triazol-4-yl) ethanedisulfonate). The trinuclear polyanions were isolated as dimethylammonium salts, and their crystal structures determined by single crystal and powder X-ray diffraction data. The polyanionic part of these salts have the same molecular structure, which consists of a linear array of metal(II) ions linked by triple N1-N2-triazole bridges. In turn, the composition and crystal packing of the MnII salt differs from the rest of the complexes (with six dimethyl ammonia as countercations) in containing one Mn+2 and four dimethyl ammonia as countercations. Magnetic data indicate dominant intramolecular antiferromagnetic interactions stabilizing a paramagnetic ground state. Susceptibility data have been successfully modeled with a simple isotropic Hamiltonian for a centrosymmetric linear trimer, H = -2J (S1S2 + S2S3) with super-exchange parameters J = -0.4 K for MnII, -7.5 K for NiII and -45 K for CuII complex. The magnetic properties of these complexes and their easy processing opens unique possibilities for their incorporation as magnetic molecular probes into such hybrid materials as magnetic/conducting multifunctional materials or as dopant for organic conducting polymers." @default.
• W3202956075 created "2021-10-11" @default.
• W3202956075 creator A5009407501 @default.
• W3202956075 creator A5028397745 @default.
• W3202956075 creator A5029156348 @default.
• W3202956075 creator A5055268790 @default.
• W3202956075 creator A5091117447 @default.
• W3202956075 date "2021-10-04" @default.
• W3202956075 modified "2023-10-17" @default.
• W3202956075 title "Crystal Structure and Magnetic Properties of Trinuclear Transition Metal Complexes (MnII, CoII, NiII and CuII) with Bridging Sulfonate-Functionalized 1,2,4-Triazole Derivatives" @default.
• W3202956075 cites W1486881477 @default.
• W3202956075 cites W1957264769 @default.
• W3202956075 cites W1973920825 @default.
• W3202956075 cites W1975444020 @default.
• W3202956075 cites W1977481624 @default.
• W3202956075 cites W1981428032 @default.
• W3202956075 cites W1986639525 @default.
• W3202956075 cites W1989869989 @default.
• W3202956075 cites W1997996968 @default.
• W3202956075 cites W1998509951 @default.
• W3202956075 cites W2001804775 @default.
• W3202956075 cites W2001908875 @default.
• W3202956075 cites W2002456976 @default.
• W3202956075 cites W2004350920 @default.
• W3202956075 cites W2005143966 @default.
• W3202956075 cites W2006219718 @default.
• W3202956075 cites W2018107847 @default.
• W3202956075 cites W2019440900 @default.
• W3202956075 cites W2019682415 @default.
• W3202956075 cites W2020630776 @default.
• W3202956075 cites W2022097022 @default.
• W3202956075 cites W2022187466 @default.
• W3202956075 cites W2028785018 @default.
• W3202956075 cites W2031918867 @default.
• W3202956075 cites W2033602806 @default.
• W3202956075 cites W2036037924 @default.
• W3202956075 cites W2039973234 @default.
• W3202956075 cites W2042530955 @default.
• W3202956075 cites W2042537747 @default.
• W3202956075 cites W2043725238 @default.
• W3202956075 cites W2049837462 @default.
• W3202956075 cites W2049944783 @default.
• W3202956075 cites W2058993536 @default.
• W3202956075 cites W2061319311 @default.
• W3202956075 cites W2061713587 @default.
• W3202956075 cites W2073372663 @default.
• W3202956075 cites W2073996476 @default.
• W3202956075 cites W2074842027 @default.
• W3202956075 cites W2076159720 @default.
• W3202956075 cites W2076288658 @default.
• W3202956075 cites W2079919858 @default.
• W3202956075 cites W2081725928 @default.
• W3202956075 cites W2089421471 @default.
• W3202956075 cites W2090673131 @default.
• W3202956075 cites W2090952946 @default.
• W3202956075 cites W2092226069 @default.
• W3202956075 cites W2093170546 @default.
• W3202956075 cites W2095564878 @default.
• W3202956075 cites W2098170264 @default.
• W3202956075 cites W2102441973 @default.
• W3202956075 cites W2112969083 @default.
• W3202956075 cites W2115023755 @default.
• W3202956075 cites W2116845980 @default.
• W3202956075 cites W2119820487 @default.
• W3202956075 cites W2129393306 @default.
• W3202956075 cites W2131997832 @default.
• W3202956075 cites W2142431169 @default.
• W3202956075 cites W2145212359 @default.
• W3202956075 cites W2157329835 @default.
• W3202956075 cites W2159069189 @default.
• W3202956075 cites W2169032606 @default.
• W3202956075 cites W2283283796 @default.
• W3202956075 cites W2413395909 @default.
• W3202956075 cites W2603360340 @default.
• W3202956075 cites W2612551964 @default.
• W3202956075 cites W2726964050 @default.
• W3202956075 cites W2746094390 @default.
• W3202956075 cites W2770672409 @default.
• W3202956075 cites W2888448546 @default.
• W3202956075 cites W2898045178 @default.
• W3202956075 cites W2969378985 @default.
• W3202956075 cites W2982222559 @default.
• W3202956075 cites W4211007953 @default.
• W3202956075 doi "https://doi.org/10.3390/molecules26196020" @default.
• W3202956075 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8512707" @default.
• W3202956075 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34641564" @default.
• W3202956075 hasPublicationYear "2021" @default.
• W3202956075 type Work @default.
• W3202956075 sameAs 3202956075 @default.
• W3202956075 citedByCount "4" @default.
• W3202956075 countsByYear W32029560752022 @default.
• W3202956075 countsByYear W32029560752023 @default.
• W3202956075 crossrefType "journal-article" @default.
• W3202956075 hasAuthorship W3202956075A5009407501 @default.
• W3202956075 hasAuthorship W3202956075A5028397745 @default.
• W3202956075 hasAuthorship W3202956075A5029156348 @default.
• W3202956075 hasAuthorship W3202956075A5055268790 @default.
• W3202956075 hasAuthorship W3202956075A5091117447 @default.

• next