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• W3202978488 abstract "The capacity of X-ray photoelectron spectroscopy (XPS) to provide information on the electronic structure of molecular organometallic complexes of Ln(II) ions (Ln = lanthanide) has been examined for the first time. XPS spectra were obtained on the air-sensitive molecular trivalent 4fn Cp'3LnIII complexes (Ln = Sm, Eu, Gd, Tb; Cp' = C5H4SiMe3) and compared to those of the highly reactive divalent complexes, [K(crypt)][Cp'3LnII] (crypt = 2.2.2-cryptand), which have either 4fn+1 (Sm, Eu) or 4fn5d1 electron configurations (Gd, Tb). The Ln 4d, Si 2p, and C 1s regions of the Ln(III) and Ln(II) complexes were identified and compared. The metal 4d peaks of these molecular lanthanide complexes were used diagnostically to compare oxidation states. The valence region of the Gd(III) and Gd(II) complexes was also examined with XPS and density function theory/random phase approximation (DFT/RPA) calculations, and this led to the tentative assignment of a signal from the 5d1 electron consistent with a 4f75d1 electron configuration for Gd(II)." @default.
• W3202978488 created "2021-10-11" @default.
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• W3202978488 date "2021-09-29" @default.
• W3202978488 modified "2023-10-16" @default.
• W3202978488 title "High-Resolution X-ray Photoelectron Spectroscopy of Organometallic (C₅H₄SiMe₃)₃Ln^III and [(C₅H₄SiMe₃)₃Ln^II]^1– Complexes (Ln = Sm, Eu, Gd, Tb)" @default.
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• W3202978488 doi "https://doi.org/10.1021/jacs.1c06980" @default.
• W3202978488 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34586787" @default.
• W3202978488 hasPublicationYear "2021" @default.
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