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- W3203003288 endingPage "1325" @default.
- W3203003288 startingPage "1321" @default.
- W3203003288 abstract "In this work, we used zwitterionic poly(4-vinylpyridine) propane-1-sulfonate (PVPS) as a constituent block to construct high χ-low N block copolymers (BCPs) with different neutral polymers as the other block, including polystyrene (PS), poly(ethylene oxide) (PEO), and poly(l-lactide) (PLLA). Lamellar structures with sub-5 nm microdomains were observed in all three types of BCPs. Due to the tendency of self-aggregation induced by electrostatic interaction in polyzwitterion, the Flory-Huggins parameters (χ) between PVPS and most neutral polymers are relatively high, which provides a facile and efficient way to fabricate high χ-low N BCPs. In addition, the dimension of the sub-5 nm structures formed in PVPS-containing BCPs showed high thermal stability with a small fluctuation (±0.1 nm) of domain spacings upon heating." @default.
- W3203003288 created "2021-10-11" @default.
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- W3203003288 date "2021-10-06" @default.
- W3203003288 modified "2023-10-18" @default.
- W3203003288 title "Fabrication of High χ-Low <i>N</i> Block Copolymers with Thermally Stable Sub-5 nm Microdomains Using Polyzwitterion as a Constituent Block" @default.
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- W3203003288 doi "https://doi.org/10.1021/acsmacrolett.1c00461" @default.
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