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- W3203155280 abstract "How does a small change in the structure of a phospholipid affect its supramolecular assembly? In aqueous suspensions, the substitution of one ester linkage in DPPC (1,2-dipalmitoyl-sn-glycero-3-phosphocholine) by an ether linkage alters its phase behaviour completely. To unravel the effect of replacing a phospholipid’s ester linkage by an ether linkage in lipid monolayers, we characterized pure monolayers of the model lipid DPPC and its sn-2 ether analogue PHPC (1-palmitoyl-2-O-hexadecyl-sn-glycero-3-phosphocholine) as well as mixtures of both by measurements of surface pressure – molecular area (π–A_mol) isotherms. In addition, we used infrared reflection absorption spectroscopy (IRRAS) and epifluorescence microscopy to study lipid condensation, lipid chain orientation, headgroup hydration, and lipid miscibility in all samples." @default.
- W3203155280 created "2021-10-11" @default.
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- W3203155280 date "2020-12-15" @default.
- W3203155280 modified "2023-09-25" @default.
- W3203155280 title "Influence of a Single Ether Bond on Assembly, Orientation, and Miscibility of Phosphocholine Lipids at the Air-Water Interface" @default.
- W3203155280 doi "https://doi.org/10.26434/chemrxiv.13370285.v1" @default.
- W3203155280 hasPublicationYear "2020" @default.
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