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- W3203735152 abstract "Disorder of doped conjugated polymers, which affects how effectively charge carriers are transported, is an important factor to be controlled to achieve high thermoelectric (TE) performance. However, experimentally controlling the disorder in highly doped polymers is difficult because of the limitations of dopant engineering. Here, by using a counter-ion exchange method, we systematically control the counter-ion-induced disorder in a highly doped state and analyze how the disorder changes the TE transport properties in poly(3,4-ethylenedioxythiophene) (PEDOT). Multi-cyano-functionalized counter-ions, which exhibit different Coulombic attraction with PEDOT, change the structural and energetic disorder in PEDOT. These changes in the disorder are evaluated with respect to several qualities of PEDOT: crystalline ordering, density of states (DOS), and polaron behaviors. Decreasing the counter-ion-induced localization of charge carriers in PEDOT increases the planarity of the PEDOT chains and narrows the DOS of PEDOT. In addition, an analysis of the number of unpaired polarons and the Curie susceptibility shows quantitatively how the charge carriers are localized by the counter-ion-induced disorder in PEDOT. These changes result in opposite behaviors of the electrical conductivity and the Seebeck coefficient in PEDOT in response to the extent of disorder and thereby produce a high figure of merit ZT of 0.21 with a remarkable power factor in the PEDOT film with the lowest degree of disorder." @default.
- W3203735152 created "2021-10-11" @default.
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- W3203735152 date "2021-12-01" @default.
- W3203735152 modified "2023-10-13" @default.
- W3203735152 title "Engineering counter-ion-induced disorder of a highly doped conjugated polymer for high thermoelectric performance" @default.
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- W3203735152 cites W1991238795 @default.
- W3203735152 cites W1995423732 @default.
- W3203735152 cites W1997292801 @default.
- W3203735152 cites W1999555977 @default.
- W3203735152 cites W2001566902 @default.
- W3203735152 cites W2004515385 @default.
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- W3203735152 cites W2012577355 @default.
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- W3203735152 cites W2022146957 @default.
- W3203735152 cites W2022190003 @default.
- W3203735152 cites W2024337470 @default.
- W3203735152 cites W2032531860 @default.
- W3203735152 cites W2033648340 @default.
- W3203735152 cites W2033658688 @default.
- W3203735152 cites W2034106433 @default.
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- W3203735152 doi "https://doi.org/10.1016/j.nanoen.2021.106604" @default.
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