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- W3203746892 abstract "Herein, we report a mild and general nickel-catalysed asymmetric reductive alkylation to effectively convert enamines—a class of important yet underexploited feedstock chemicals—into drug-like α-branched chiral amines and derivatives. This reaction involves the regio- and stereoselective hydrometallation of an enamine to generate a catalytic amount of enantioenriched alkylnickel intermediate, followed by C–C bond formation via alkyl electrophiles." @default.
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- W3203746892 date "2020-10-16" @default.
- W3203746892 modified "2023-10-18" @default.
- W3203746892 title "Catalytic Asymmetric Reductive Alkylation of Enamines to Chiral Aliphatic Amines" @default.
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- W3203746892 doi "https://doi.org/10.26434/chemrxiv.13102307.v1" @default.
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