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- W3203777881 abstract "A tricarboxylate supported binuclear metal organic hybrids of Cu(II), [Cu 2 ( µ -cit)(phen) 4 ]·9H 2 O ( 1 ) has been synthesized using well known pyridyl based N , N ′ linker, 1,10-phenanthroline and has been structurally characterized. The use of the flexible hydroxyl tricarboxylate, citrate, in designing such framework has created a marked diversity in the topology. The structural and topological diversity has been analyzed from the single crystal X-ray structure. Here, in an unit, each of the two Cu(II) centres are chelated by two phenanthrolineligands and citrate (cit 4- ) serves the role of a bridging ligand. Furthermore, the carboxylate moiety/hydroxyl oxygen sites of citrate and the aromatic chelating ligands promote the supramolecular recognition through hydrogen bonding and other non-covalent interactions (like π-π interaction) and thereby results in higher dimensional architecture.Along with this, there are water molecules as water of crystallization. The oxygen atoms of the carboxylate moiety involve in both inter and intra-molecular hydrogen bonding with the hydrogen atoms of the water molecules resulting in a hydrogen bonded helical supramolecular solid. Theoretical study is performed to analyze the structure and the role of non-covalent interactions through DFT based calculations and Hirshfeld surface analysis." @default.
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- W3203777881 date "2018-04-01" @default.
- W3203777881 modified "2023-09-23" @default.
- W3203777881 title "Hydrogen bonded supramolecular architecture of a copper(II)-citrate coordination building block: Synthesis and crystal structure with theoretical insight" @default.
- W3203777881 hasPublicationYear "2018" @default.
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