Matches in SemOpenAlex for { <https://semopenalex.org/work/W3203902012> ?p ?o ?g. }
- W3203902012 endingPage "25845" @default.
- W3203902012 startingPage "25839" @default.
- W3203902012 abstract "The active site of [FeFe]-hydrogenase (H2 ase) is preorganized with an amine (azadithiolate) as a proton relay and a [4Fe4S] subunit as an electron reservoir, which together lower the overpotential for proton reduction and hydrogen oxidation by multiple-site concerted proton-electron transfer (MS-CPET). Herein, we report a mononuclear manganese complex, fac-[Mn(CO)3 (6-(2-hydroxyphenol)-2-pyridine-2-quinoline) Br] (1), as a rare model to fully mimic the functions of the H2 ase. In 1, a redox-active bidentate ligand with a pendent phenol replicates the roles of the electron reservoir and the proton relay in the enzyme. Experimental and theoretical studies revealed two consecutive MS-CPET processes in the catalytic cycle, in each of which an electron stored in the reductive ligand and a proton at the proximal phenol moiety are transferred to the Mn center in a concerted way. By virtue of this mechanism, complex 1 exhibited a low overpotential comparable to that of natural enzyme in electrochemical hydrogen production using phenol as a proton source." @default.
- W3203902012 created "2021-10-11" @default.
- W3203902012 creator A5002661071 @default.
- W3203902012 creator A5004948530 @default.
- W3203902012 creator A5005228021 @default.
- W3203902012 creator A5008576475 @default.
- W3203902012 creator A5010513055 @default.
- W3203902012 creator A5018967285 @default.
- W3203902012 creator A5041998803 @default.
- W3203902012 creator A5055151897 @default.
- W3203902012 creator A5065366426 @default.
- W3203902012 creator A5078143614 @default.
- W3203902012 creator A5083967189 @default.
- W3203902012 date "2021-11-05" @default.
- W3203902012 modified "2023-10-18" @default.
- W3203902012 title "Multiple‐Site Concerted Proton–Electron Transfer in a Manganese‐Based Complete Functional Model for [FeFe]‐Hydrogenase" @default.
- W3203902012 cites W2019007515 @default.
- W3203902012 cites W2027496857 @default.
- W3203902012 cites W2038312285 @default.
- W3203902012 cites W2046896984 @default.
- W3203902012 cites W2056872218 @default.
- W3203902012 cites W2065818181 @default.
- W3203902012 cites W2081758854 @default.
- W3203902012 cites W2102207213 @default.
- W3203902012 cites W2129711615 @default.
- W3203902012 cites W2140610680 @default.
- W3203902012 cites W2142074026 @default.
- W3203902012 cites W2150308424 @default.
- W3203902012 cites W2156937433 @default.
- W3203902012 cites W2295040326 @default.
- W3203902012 cites W2328034507 @default.
- W3203902012 cites W2333381434 @default.
- W3203902012 cites W2418820343 @default.
- W3203902012 cites W2469190439 @default.
- W3203902012 cites W2531975196 @default.
- W3203902012 cites W2576580843 @default.
- W3203902012 cites W2581587902 @default.
- W3203902012 cites W2606764133 @default.
- W3203902012 cites W2614048962 @default.
- W3203902012 cites W2835456725 @default.
- W3203902012 cites W2886746176 @default.
- W3203902012 cites W2891145257 @default.
- W3203902012 cites W2891748764 @default.
- W3203902012 cites W2901231321 @default.
- W3203902012 cites W2908722217 @default.
- W3203902012 cites W2913853938 @default.
- W3203902012 cites W2936418497 @default.
- W3203902012 cites W2936699243 @default.
- W3203902012 cites W2967809110 @default.
- W3203902012 cites W2970903860 @default.
- W3203902012 cites W2973113418 @default.
- W3203902012 cites W3004537788 @default.
- W3203902012 cites W3048997561 @default.
- W3203902012 cites W3118324056 @default.
- W3203902012 cites W3135437241 @default.
- W3203902012 cites W4230266322 @default.
- W3203902012 doi "https://doi.org/10.1002/anie.202106983" @default.
- W3203902012 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34595813" @default.
- W3203902012 hasPublicationYear "2021" @default.
- W3203902012 type Work @default.
- W3203902012 sameAs 3203902012 @default.
- W3203902012 citedByCount "6" @default.
- W3203902012 countsByYear W32039020122022 @default.
- W3203902012 countsByYear W32039020122023 @default.
- W3203902012 crossrefType "journal-article" @default.
- W3203902012 hasAuthorship W3203902012A5002661071 @default.
- W3203902012 hasAuthorship W3203902012A5004948530 @default.
- W3203902012 hasAuthorship W3203902012A5005228021 @default.
- W3203902012 hasAuthorship W3203902012A5008576475 @default.
- W3203902012 hasAuthorship W3203902012A5010513055 @default.
- W3203902012 hasAuthorship W3203902012A5018967285 @default.
- W3203902012 hasAuthorship W3203902012A5041998803 @default.
- W3203902012 hasAuthorship W3203902012A5055151897 @default.
- W3203902012 hasAuthorship W3203902012A5065366426 @default.
- W3203902012 hasAuthorship W3203902012A5078143614 @default.
- W3203902012 hasAuthorship W3203902012A5083967189 @default.
- W3203902012 hasConcept C110010208 @default.
- W3203902012 hasConcept C116569031 @default.
- W3203902012 hasConcept C123669783 @default.
- W3203902012 hasConcept C147789679 @default.
- W3203902012 hasConcept C161790260 @default.
- W3203902012 hasConcept C170493617 @default.
- W3203902012 hasConcept C17525397 @default.
- W3203902012 hasConcept C178790620 @default.
- W3203902012 hasConcept C179104552 @default.
- W3203902012 hasConcept C185592680 @default.
- W3203902012 hasConcept C186460083 @default.
- W3203902012 hasConcept C2776309666 @default.
- W3203902012 hasConcept C41183919 @default.
- W3203902012 hasConcept C52859227 @default.
- W3203902012 hasConcept C55493867 @default.
- W3203902012 hasConcept C55904794 @default.
- W3203902012 hasConcept C75473681 @default.
- W3203902012 hasConcept C79115784 @default.
- W3203902012 hasConceptScore W3203902012C110010208 @default.
- W3203902012 hasConceptScore W3203902012C116569031 @default.
- W3203902012 hasConceptScore W3203902012C123669783 @default.
- W3203902012 hasConceptScore W3203902012C147789679 @default.