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- W3204015109 abstract "Abstract 3,7,23,27‐Tetrabromo[36]octaphyrin 2 was synthesized as a novel octaphyrin bearing two meso ‐free positions. Surprisingly, its Zn II and Ni II complexation reactions produced a directly fused porphyrin(2.1.1.1) dimer 6 , and a meso‐α fused N‐confused porphyrin (NCP) dimer 7 , as the first example of NCP tape, respectively, via transannular C−C bond formation. While 6 exhibits a diatropic ring‐current effect owing to the global 36π Möbius aromaticity, 7 shows a paratropic ring‐current effect due to the global Hückel 36π antiaromaticity. In addition, the oxidation of 7 with PbO 2 allowed for formation of its two‐electron oxidized species 9 that exhibited a diatropic ring‐current effect due to the global Hückel 34π aromaticity. This work has demonstrated that meso ‐free large expanded porphyrins can be a promising platform to produce novel fused porphyrinoids." @default.
- W3204015109 created "2021-10-11" @default.
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- W3204015109 date "2021-11-09" @default.
- W3204015109 modified "2023-09-26" @default.
- W3204015109 title "Tetrabromo[36]octaphyrin: A Promising Precursor of Directly Fused Porphyrin(2.1.1.1) Dimer and <i>meso‐α</i> Fused N‐Confused Porphyrin Dimer" @default.
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- W3204015109 doi "https://doi.org/10.1002/ange.202112023" @default.
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