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- W3204015390 abstract "By using a chiral directing group, an asymmetric rhodium(III)-catalyzed C-H bond addition to aldimines followed by intramolecular cyclization to form chiral isoindolinones has been achieved (up to 68 % yield, up to 93 % ee). A three-component variant that resembles Mannich reaction was also realized (41 % yield, 83 % ee). Product elaborations and preliminary mechanistic studies were described." @default.
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- W3204015390 date "2021-10-13" @default.
- W3204015390 modified "2023-10-10" @default.
- W3204015390 title "Chiral‐Directing‐Group‐Assisted Rhodium(III)‐Catalyzed Asymmetric Addition of Inert Arene C−H Bond to Aldimines with Subsequent Intramolecular Cyclization" @default.
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- W3204015390 doi "https://doi.org/10.1002/chem.202103319" @default.
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