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- W3204105745 abstract "The cover picture shows a dramatic color change when a 1-(dibutylstannyl)-1,4-diphenylbutadiene derivative fused with a dibenzobarrelene skeleton is treated with BuLi. A large high-field shift from 22 ppm to –229 ppm in 119Sn NMR shows the formation of the corresponding five-coordinated lithium stannate. The deep-red color is due to the weak long-wavelength absorption centered at 471 nm. TD-DFT calculations exhibit that the absorption is brought by the excitation mainly from HOMO (σ bonds of the hypervalent tin moiety) to LUMO (π* orbital of the 1,4-diphenylbutadiene moiety)(see article 202100227)." @default.
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- W3204105745 date "2021-10-01" @default.
- W3204105745 modified "2023-10-17" @default.
- W3204105745 title "Front Cover: Synthesis and Properties of 1‐(Dialkylstannyl)‐1,4‐diphenyl‐1,3‐butadiene Fused with a Dibenzobarrelene and the Corresponding Pentaorganostannate (Z. Anorg. Allg. Chem. 19/2021)" @default.
- W3204105745 doi "https://doi.org/10.1002/zaac.202100289" @default.
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