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• W3204122714 abstract "Vinylallenes have been recognized as versatile C2 and C4 components for nickel-catalyzed intramolecular [4+2] and [2+2] cycloadditions. The former reaction was promoted by a Ni(0) complex (up to quantitative yield), and a Ni(II) salt was a key species for the latter reaction to give the corresponding regio- and stereocontrolled cycloadducts (up to 88% yield). DFT studies revealed that both reaction pathways involve a concerted mechanism through the activation of different C-C multiple bonds in the substrates." @default.
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• W3204122714 date "2021-01-01" @default.
• W3204122714 modified "2023-09-26" @default.
• W3204122714 title "Regio-divergent nickel catalysis: intramolecular [4+2] and [2+2] cycloaddition reactions between vinylallenes and alkynes" @default.
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• W3204122714 doi "https://doi.org/10.1039/d1cc03942c" @default.
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