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- W3204132976 abstract "A highly stereoselective synthesis of (E)-δ-boryl-anti-homoallylic alcohols is developed. In the presence of a Lewis acid, aldehyde allylation with α-boryl-(E)-crotylboronate gave δ-boryl-anti-homoallylic alcohols in good yields with excellent E-selectivity. The E-vinylboronate group in the products provides a useful handle for cross-coupling reactions as illustrated in the fragment synthesis of chaxamycins." @default.
- W3204132976 created "2021-10-11" @default.
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- W3204132976 date "2021-01-01" @default.
- W3204132976 modified "2023-10-14" @default.
- W3204132976 title "Highly stereoselective syntheses of (<i>E</i>)-δ-boryl-<i>anti</i>-homoallylic alcohols <i>via</i> allylation with α-boryl-(<i>E</i>)-crotylboronate" @default.
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- W3204132976 doi "https://doi.org/10.1039/d1cc04058h" @default.
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