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- W3204145983 endingPage "131627" @default.
- W3204145983 startingPage "131627" @default.
- W3204145983 abstract "A new Cu(II) coordination polymer with formula {[Cu(L)(bbi)(H2O)]•H2O}n (1) (H2L = 1,3-bis(3ˊ-carboxylatophenoxy)benzene, bbi = 1,1′-(1,4-butanediyl)bis(imidazole)), has been prepared and characterized using microanalysis, single crystal and powder X-ray diffraction techniques. The polymer 1 possess 1D double chain, which further extends into 2D layer through packing and hydrogen bond interactions. The polymer has been used as an effective photocatalyst for the photodisintegration of aromatic dyes viz. methyl violet (MV), Rhodamine B (Rh B) and methylene blue (MB). The results suggest that 1 is best photocatalyst for MB and decomposed 84.14% MB in 100 min following pseudo-first order reaction with rate constant k 0.01873 min−1. Furthermore, the possible photocatalytic mechanism exhibited by 1 for the catalytic degradation of MB was proposed using the trapping experiments and LC-MS methodology which suggested that ·OH is the main reactive oxygen species involved in photodecomposition of MB. In addition, band gap calculations and Hirshfeld surface analysis have been done to substantiate the photocatalytic mechanism." @default.
- W3204145983 created "2021-10-11" @default.
- W3204145983 creator A5038368004 @default.
- W3204145983 creator A5040380875 @default.
- W3204145983 creator A5056036725 @default.
- W3204145983 creator A5064559096 @default.
- W3204145983 creator A5074579647 @default.
- W3204145983 creator A5074942308 @default.
- W3204145983 creator A5084175244 @default.
- W3204145983 creator A5089713791 @default.
- W3204145983 date "2022-02-01" @default.
- W3204145983 modified "2023-09-26" @default.
- W3204145983 title "A new Cu(II) metal–organic architecture driven by ether-bridged dicarboxylate: Photocatalytic properties and Hirshfeld surface analysis" @default.
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