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- W3204181814 endingPage "26356" @default.
- W3204181814 startingPage "26351" @default.
- W3204181814 abstract "By using copper(I) homoenolates as nucleophiles, which are generated through the ring-opening of 1-substituted cyclopropane-1-ols, a catalytic asymmetric allylic substitution with allyl phosphates is achieved in high to excellent yields with high enantioselectivity. Both 1-substituted cyclopropane-1-ols and allylic phosphates enjoy broad substrate scopes. Remarkably, various functional groups, such as ether, ester, tosylate, imide, alcohol, nitro, and carbamate are well tolerated. Moreover, the present method is nicely extended to the asymmetric construction of quaternary carbon centers. Some control experiments argue against a radical-based reaction mechanism and a catalytic cycle based on a two-electron process is proposed. Finally, the synthetic utilities of the product are showcased by means of the transformations of the terminal olefin group and the ketone group." @default.
- W3204181814 created "2021-10-11" @default.
- W3204181814 creator A5006651916 @default.
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- W3204181814 creator A5045313060 @default.
- W3204181814 creator A5053203813 @default.
- W3204181814 date "2021-11-03" @default.
- W3204181814 modified "2023-09-27" @default.
- W3204181814 title "Catalytic Asymmetric Allylic Substitution with Copper(I) Homoenolates Generated from Cyclopropanols" @default.
- W3204181814 cites W1021019411 @default.
- W3204181814 cites W1511810299 @default.
- W3204181814 cites W1547708927 @default.
- W3204181814 cites W1552045685 @default.
- W3204181814 cites W1826380312 @default.
- W3204181814 cites W1967993282 @default.
- W3204181814 cites W1971406006 @default.
- W3204181814 cites W1973741554 @default.
- W3204181814 cites W1982120442 @default.
- W3204181814 cites W1995442643 @default.
- W3204181814 cites W2002718914 @default.
- W3204181814 cites W2004473698 @default.
- W3204181814 cites W2006102769 @default.
- W3204181814 cites W2009707489 @default.
- W3204181814 cites W2031991029 @default.
- W3204181814 cites W2044661599 @default.
- W3204181814 cites W2059997435 @default.
- W3204181814 cites W2094257082 @default.
- W3204181814 cites W2099341182 @default.
- W3204181814 cites W2103349595 @default.
- W3204181814 cites W2106619994 @default.
- W3204181814 cites W2111741771 @default.
- W3204181814 cites W2122390638 @default.
- W3204181814 cites W2129183887 @default.
- W3204181814 cites W2132004336 @default.
- W3204181814 cites W2143019367 @default.
- W3204181814 cites W2149452392 @default.
- W3204181814 cites W2152979979 @default.
- W3204181814 cites W2165583917 @default.
- W3204181814 cites W2170029991 @default.
- W3204181814 cites W2270025540 @default.
- W3204181814 cites W2282164418 @default.
- W3204181814 cites W2294606986 @default.
- W3204181814 cites W2312596748 @default.
- W3204181814 cites W2315497070 @default.
- W3204181814 cites W2318039429 @default.
- W3204181814 cites W2319029112 @default.
- W3204181814 cites W2321819434 @default.
- W3204181814 cites W2324611410 @default.
- W3204181814 cites W2333499804 @default.
- W3204181814 cites W2334228848 @default.
- W3204181814 cites W2341277486 @default.
- W3204181814 cites W2498108076 @default.
- W3204181814 cites W2546596170 @default.
- W3204181814 cites W2567027422 @default.
- W3204181814 cites W2580206951 @default.
- W3204181814 cites W2600645865 @default.
- W3204181814 cites W2604909098 @default.
- W3204181814 cites W2610200321 @default.
- W3204181814 cites W2761043211 @default.
- W3204181814 cites W2766631857 @default.
- W3204181814 cites W2789846977 @default.
- W3204181814 cites W2801934940 @default.
- W3204181814 cites W281214914 @default.
- W3204181814 cites W2891807423 @default.
- W3204181814 cites W2900540320 @default.
- W3204181814 cites W2918205503 @default.
- W3204181814 cites W2945915625 @default.
- W3204181814 cites W2947538552 @default.
- W3204181814 cites W2950975549 @default.
- W3204181814 cites W2952983720 @default.
- W3204181814 cites W2953193022 @default.
- W3204181814 cites W2958003267 @default.
- W3204181814 cites W3012082576 @default.
- W3204181814 cites W3036180490 @default.
- W3204181814 cites W3045877662 @default.
- W3204181814 cites W3092114000 @default.
- W3204181814 cites W3093912291 @default.
- W3204181814 cites W3096160990 @default.
- W3204181814 cites W3106911697 @default.
- W3204181814 cites W3119976436 @default.
- W3204181814 cites W3136846868 @default.
- W3204181814 cites W3186158251 @default.
- W3204181814 cites W4230875050 @default.
- W3204181814 cites W4231507874 @default.
- W3204181814 cites W4233742870 @default.
- W3204181814 cites W4237096166 @default.
- W3204181814 cites W4237198454 @default.
- W3204181814 cites W4239125106 @default.
- W3204181814 cites W4245588027 @default.
- W3204181814 cites W4248788824 @default.
- W3204181814 cites W4249026267 @default.
- W3204181814 cites W4251327099 @default.
- W3204181814 cites W4251338379 @default.
- W3204181814 cites W4253878142 @default.
- W3204181814 cites W4254134881 @default.
- W3204181814 cites W4255740026 @default.
- W3204181814 cites W4256565413 @default.
- W3204181814 cites W4367275817 @default.