Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204184595> ?p ?o ?g. }
- W3204184595 endingPage "797" @default.
- W3204184595 startingPage "775" @default.
- W3204184595 abstract "A free energy-based conceptual theoretical framework from which the conditional equilibrium constant can be comprehensibly understood is presented. This constant is found to be a weighted geometric mean of the equilibrium constants of the reactions of all forms of the conditioned species under buffering conditions, where the weight is given by a function of their predominance in terms of their mole fractions. Once it is shown that this type of equilibrium constant can be easily deduced form free energy functions, it is shown how corrections for activity coefficient can be incorporated as well. The framework additionally permits to interpret side-reactions coefficients as free energy terms related to the chemical speciation of the system, allowing the use of the generalization of Hess' law to obtain conditional constants and a straightforward deduction of multiconditional equilibrium constants. Furthermore, different uses of the conditional constants along the actual literature are reviewed as well allowing to have a complete and updated panorama of the employment of this important concept in chemical and speciation analysis in many areas of research." @default.
- W3204184595 created "2021-10-11" @default.
- W3204184595 creator A5043243647 @default.
- W3204184595 creator A5061523259 @default.
- W3204184595 creator A5068277209 @default.
- W3204184595 date "2021-10-03" @default.
- W3204184595 modified "2023-10-01" @default.
- W3204184595 title "Conditional Equilibrium Constants Reviewed" @default.
- W3204184595 cites W124582669 @default.
- W3204184595 cites W1433125301 @default.
- W3204184595 cites W1489587289 @default.
- W3204184595 cites W1503187796 @default.
- W3204184595 cites W1588877075 @default.
- W3204184595 cites W162351077 @default.
- W3204184595 cites W1637123222 @default.
- W3204184595 cites W1816412093 @default.
- W3204184595 cites W1965330093 @default.
- W3204184595 cites W1965546151 @default.
- W3204184595 cites W1965720012 @default.
- W3204184595 cites W1966817155 @default.
- W3204184595 cites W1966874094 @default.
- W3204184595 cites W1967525243 @default.
- W3204184595 cites W1969211203 @default.
- W3204184595 cites W1969308919 @default.
- W3204184595 cites W1970400170 @default.
- W3204184595 cites W1970816156 @default.
- W3204184595 cites W1973085831 @default.
- W3204184595 cites W1980249464 @default.
- W3204184595 cites W1980859640 @default.
- W3204184595 cites W1982178290 @default.
- W3204184595 cites W1984952776 @default.
- W3204184595 cites W1985308889 @default.
- W3204184595 cites W1986332753 @default.
- W3204184595 cites W1986459210 @default.
- W3204184595 cites W1990629709 @default.
- W3204184595 cites W1990697359 @default.
- W3204184595 cites W1991742545 @default.
- W3204184595 cites W1994342874 @default.
- W3204184595 cites W1994879661 @default.
- W3204184595 cites W1996284228 @default.
- W3204184595 cites W1996728286 @default.
- W3204184595 cites W1997966159 @default.
- W3204184595 cites W2000125137 @default.
- W3204184595 cites W2002404224 @default.
- W3204184595 cites W2002475431 @default.
- W3204184595 cites W2004279376 @default.
- W3204184595 cites W2005424462 @default.
- W3204184595 cites W2008562790 @default.
- W3204184595 cites W2008664130 @default.
- W3204184595 cites W2009250323 @default.
- W3204184595 cites W2013565049 @default.
- W3204184595 cites W2015085959 @default.
- W3204184595 cites W2018172874 @default.
- W3204184595 cites W2020136744 @default.
- W3204184595 cites W2022360027 @default.
- W3204184595 cites W2023618391 @default.
- W3204184595 cites W2027302419 @default.
- W3204184595 cites W2029262281 @default.
- W3204184595 cites W2032975025 @default.
- W3204184595 cites W2035106109 @default.
- W3204184595 cites W2035249291 @default.
- W3204184595 cites W2035507964 @default.
- W3204184595 cites W2035885448 @default.
- W3204184595 cites W2036739160 @default.
- W3204184595 cites W2037743735 @default.
- W3204184595 cites W2038141983 @default.
- W3204184595 cites W2038654725 @default.
- W3204184595 cites W2039580629 @default.
- W3204184595 cites W2040506379 @default.
- W3204184595 cites W2041462552 @default.
- W3204184595 cites W2043752617 @default.
- W3204184595 cites W2043823056 @default.
- W3204184595 cites W2047568613 @default.
- W3204184595 cites W2048325386 @default.
- W3204184595 cites W2049289630 @default.
- W3204184595 cites W2050002493 @default.
- W3204184595 cites W2051464172 @default.
- W3204184595 cites W2054037824 @default.
- W3204184595 cites W2055472035 @default.
- W3204184595 cites W2055989854 @default.
- W3204184595 cites W2056200652 @default.
- W3204184595 cites W2056204989 @default.
- W3204184595 cites W2060437861 @default.
- W3204184595 cites W2062016800 @default.
- W3204184595 cites W2062856489 @default.
- W3204184595 cites W2063176357 @default.
- W3204184595 cites W2063436104 @default.
- W3204184595 cites W2065724539 @default.
- W3204184595 cites W2066789259 @default.
- W3204184595 cites W2069905487 @default.
- W3204184595 cites W2069993098 @default.
- W3204184595 cites W2071064826 @default.
- W3204184595 cites W2071791912 @default.
- W3204184595 cites W2072223332 @default.
- W3204184595 cites W2072819792 @default.
- W3204184595 cites W2072873069 @default.
- W3204184595 cites W2073427289 @default.
- W3204184595 cites W2075950607 @default.