FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204194599> ?p ?o ?g. }

• W3204194599 abstract "Structural analyses of the compounds di-μ-acetato-κ4O:O'-bis-{[2-meth-oxy-N,N-bis-(quinolin-2-ylmeth-yl)ethanamine-κ4N,N',N'',O]manganese(II)} bis-(tetra-phen-yl-borate) di-chloro-methane 1.45-solvate, [Mn2(C23O2)2(C23H23N3O)2](C24H20B)·1.45CH2Cl2 or [Mn(DQMEA)(μ-OAc)2Mn(DQMEA)](BPh4)2·1.45CH2Cl2 or [1](BPh4)2·1.45CH2Cl2, and (acetato-κO)[2-hy-droxy-N,N-bis(quinolin-2-ylmeth-yl)ethanamine-κ4N,N',N'',O](methanol-κO)manganese(II) tetra-phenyl-borate methanol monosolvate, [Mn(CH3COO)(C22H21N3O)(CH3OH)](C24H20B)·CH3OH or [Mn(DQEA)(OAc)(CH3OH)]BPh4·CH3OH or [2]BPh4·CH3OH, by single-crystal X-ray diffraction reveal distinct differences in the geometry of coordination of the tripodal DQEA and DQMEA ligands to MnII ions. In the asymmetric unit, compound [1](BPh4)2·(CH2Cl2)1.45 crystallizes as a dimer in which each manganese(II) center is coordinated by the central amine nitro-gen, the nitro-gen atom of each quinoline group, and the meth-oxy-oxygen of the tetra-dentate DQMEA ligand, and two bridging-acetate oxygen atoms. The symmetric MnII centers have a distorted, octa-hedral geometry in which the quinoline nitro-gen atoms are trans to each other resulting in co-planarity of the quinoline rings. For each MnII center, a coordinated acetate oxygen participates in C-H⋯O hydrogen-bonding inter-actions with the two quinolyl moieties, further stabilizing the trans structure. Within the crystal, weak π-π stacking inter-actions and inter-molecular cation-anion inter-actions stabilize the crystal packing. In the asymmetric unit, compound [2]BPh4·CH3OH crystallizes as a monomer in which the manganese(II) ion is coordinated to the central nitro-gen, the nitro-gen atom of each quinoline group, and the alcohol oxygen of the tetra-dentate DQEA ligand, an oxygen atom of OAc, and the oxygen atom of a methanol ligand. The geometry of the MnII center in [2]BPh4·CH3OH is also a distorted octa-hedron, but the quinoline nitro-gen atoms are cis to each other in this structure. Hydrogen bonding between the acetate oxygen atoms and hydroxyl (O-H⋯O) and quinolyl (C-H⋯O and N-H⋯O) moieties of the DQEA ligand stabilize the complex in this cis configuration. Within the crystal, dimerization of complexes occurs by the formation of a pair of inter-molecular O3-H3⋯O2 hydrogen bonds between the coordinated hydroxyl oxygen of the DQEA ligand of one complex and an acetate oxygen of another. Additional hydrogen-bonding and inter-molecular cation-anion inter-actions contribute to the crystal packing." @default.
• W3204194599 created "2021-10-11" @default.
• W3204194599 creator A5007862055 @default.
• W3204194599 creator A5008905260 @default.
• W3204194599 creator A5008914681 @default.
• W3204194599 creator A5024835806 @default.
• W3204194599 creator A5029378896 @default.
• W3204194599 creator A5039577417 @default.
• W3204194599 creator A5049352342 @default.
• W3204194599 creator A5084680231 @default.
• W3204194599 date "2021-09-28" @default.
• W3204194599 modified "2023-10-12" @default.
• W3204194599 title "Geometrical variations of two manganese(II) complexes with closely related quinoline-based tripodal ligands" @default.
• W3204194599 cites W1968044936 @default.
• W3204194599 cites W1987096917 @default.
• W3204194599 cites W1987652673 @default.
• W3204194599 cites W1994430394 @default.
• W3204194599 cites W1997469061 @default.
• W3204194599 cites W2000887216 @default.
• W3204194599 cites W2010060281 @default.
• W3204194599 cites W2017838738 @default.
• W3204194599 cites W2053807549 @default.
• W3204194599 cites W2059205366 @default.
• W3204194599 cites W2072888691 @default.
• W3204194599 cites W2082159470 @default.
• W3204194599 cites W2100951378 @default.
• W3204194599 cites W2161536039 @default.
• W3204194599 cites W2247895134 @default.
• W3204194599 cites W2326196229 @default.
• W3204194599 cites W2794486673 @default.
• W3204194599 cites W2890013071 @default.
• W3204194599 cites W2940804651 @default.
• W3204194599 cites W3039749820 @default.
• W3204194599 cites W3041762147 @default.
• W3204194599 cites W3117122044 @default.
• W3204194599 doi "https://doi.org/10.1107/s2056989021009786" @default.
• W3204194599 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8491528" @default.
• W3204194599 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34667623" @default.
• W3204194599 hasPublicationYear "2021" @default.
• W3204194599 type Work @default.
• W3204194599 sameAs 3204194599 @default.
• W3204194599 citedByCount "0" @default.
• W3204194599 crossrefType "journal-article" @default.
• W3204194599 hasAuthorship W3204194599A5007862055 @default.
• W3204194599 hasAuthorship W3204194599A5008905260 @default.
• W3204194599 hasAuthorship W3204194599A5008914681 @default.
• W3204194599 hasAuthorship W3204194599A5024835806 @default.
• W3204194599 hasAuthorship W3204194599A5029378896 @default.
• W3204194599 hasAuthorship W3204194599A5039577417 @default.
• W3204194599 hasAuthorship W3204194599A5049352342 @default.
• W3204194599 hasAuthorship W3204194599A5084680231 @default.
• W3204194599 hasBestOaLocation W32041945991 @default.
• W3204194599 hasConcept C112887158 @default.
• W3204194599 hasConcept C115624301 @default.
• W3204194599 hasConcept C155647269 @default.
• W3204194599 hasConcept C178790620 @default.
• W3204194599 hasConcept C185592680 @default.
• W3204194599 hasConcept C194196696 @default.
• W3204194599 hasConcept C2776309666 @default.
• W3204194599 hasConcept C2779546866 @default.
• W3204194599 hasConcept C2780263894 @default.
• W3204194599 hasConcept C2780639532 @default.
• W3204194599 hasConcept C32909587 @default.
• W3204194599 hasConcept C528890316 @default.
• W3204194599 hasConcept C71240020 @default.
• W3204194599 hasConcept C8010536 @default.
• W3204194599 hasConceptScore W3204194599C112887158 @default.
• W3204194599 hasConceptScore W3204194599C115624301 @default.
• W3204194599 hasConceptScore W3204194599C155647269 @default.
• W3204194599 hasConceptScore W3204194599C178790620 @default.
• W3204194599 hasConceptScore W3204194599C185592680 @default.
• W3204194599 hasConceptScore W3204194599C194196696 @default.
• W3204194599 hasConceptScore W3204194599C2776309666 @default.
• W3204194599 hasConceptScore W3204194599C2779546866 @default.
• W3204194599 hasConceptScore W3204194599C2780263894 @default.
• W3204194599 hasConceptScore W3204194599C2780639532 @default.
• W3204194599 hasConceptScore W3204194599C32909587 @default.
• W3204194599 hasConceptScore W3204194599C528890316 @default.
• W3204194599 hasConceptScore W3204194599C71240020 @default.
• W3204194599 hasConceptScore W3204194599C8010536 @default.
• W3204194599 hasFunder F4320306076 @default.
• W3204194599 hasIssue "10" @default.
• W3204194599 hasLocation W32041945991 @default.
• W3204194599 hasLocation W32041945992 @default.
• W3204194599 hasLocation W32041945993 @default.
• W3204194599 hasOpenAccess W3204194599 @default.
• W3204194599 hasPrimaryLocation W32041945991 @default.
• W3204194599 hasRelatedWork W12217940 @default.
• W3204194599 hasRelatedWork W16662967 @default.
• W3204194599 hasRelatedWork W17550854 @default.
• W3204194599 hasRelatedWork W17930923 @default.
• W3204194599 hasRelatedWork W27872911 @default.
• W3204194599 hasRelatedWork W5742576 @default.
• W3204194599 hasRelatedWork W7820746 @default.
• W3204194599 hasRelatedWork W12739745 @default.
• W3204194599 hasRelatedWork W27033090 @default.
• W3204194599 hasRelatedWork W7058088 @default.
• W3204194599 hasVolume "77" @default.
• W3204194599 isParatext "false" @default.
• W3204194599 isRetracted "false" @default.

• next