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• W3204251546 endingPage "100182" @default.
• W3204251546 startingPage "100182" @default.
• W3204251546 abstract "The reaction of (Z)-2-(phenyl(2-(pyridin-2-yl)hydrazono)methyl)pyridine (L) and copper(II) salt in methanol yields a series of five pentacoordinated mononuclear complexes. The molecular formulations of these complexes are as [Cu(L)(ImH)2](ClO4)2 (1), [Cu(L)(2-MeImH)2](ClO4)2 (2), [Cu(L)(2-EthImH)2](ClO4)2 (3), [Cu(L)(BenzImH)2](ClO4)2 (4) and [Cu(L)(2-MeBenzImH)2](ClO4)2 (5) (where ImH ​= ​Imidazole, 2-MeImH ​= ​2-Methylimidazole, 2-EthImH ​= ​2-Ethylimidazole, BenzImH ​= ​Benzimidazole, 2-MeBenzImH ​= ​2-Methylbenzimidazole). The room temperature magnetic moment values are in the range 1.79–1.81 B ​M. The conductance measurements suggest that they are electrolytic in nature. The DFT calculations were performed to get information about the structures of the complexes. The copper(II) centre in all complexes is a Penta-coordinated. The proligand has NNN donor sites viz., two pyridine N and one azomethine N atoms, whereas co-ligand coordinates through pyridine N atom forming two five-membered chelate rings. The τ5 values of these complexes are in the range 0.177–0.495. Both pro and co-ligands are neutral. X-band Epr spectral measurements have been carried out to authenticate the paramagnetic behaviours of all complexes. The stability of the copper(II) centre was examined using cyclic and differential pulse Voltammetry. The IC50 and SOD activity values for all complexes reveal that they are good SOD active complexes. The IC50 value of present complexes remains in the range 26–43 ​μM." @default.
• W3204251546 created "2021-10-11" @default.
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• W3204251546 date "2021-11-01" @default.
• W3204251546 modified "2023-09-24" @default.
• W3204251546 title "Synthesis and characterization of penta-coordinated copper(II) complexes with hydrazido based ligand and imidazole as auxiliary ligand" @default.
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• W3204251546 cites W1965173894 @default.
• W3204251546 cites W1968339413 @default.
• W3204251546 cites W1971026142 @default.
• W3204251546 cites W1972016476 @default.
• W3204251546 cites W1972493784 @default.
• W3204251546 cites W1973111787 @default.
• W3204251546 cites W1978799030 @default.
• W3204251546 cites W1978830847 @default.
• W3204251546 cites W1989226995 @default.
• W3204251546 cites W1989475263 @default.
• W3204251546 cites W1989792857 @default.
• W3204251546 cites W1991999504 @default.
• W3204251546 cites W1992446397 @default.
• W3204251546 cites W1995920569 @default.
• W3204251546 cites W1998722626 @default.
• W3204251546 cites W2003067321 @default.
• W3204251546 cites W2004112993 @default.
• W3204251546 cites W2005825639 @default.
• W3204251546 cites W2005856406 @default.
• W3204251546 cites W2006725984 @default.
• W3204251546 cites W2009161411 @default.
• W3204251546 cites W2011680032 @default.
• W3204251546 cites W2015365491 @default.
• W3204251546 cites W2017829543 @default.
• W3204251546 cites W2020127134 @default.
• W3204251546 cites W2022357672 @default.
• W3204251546 cites W2032493122 @default.
• W3204251546 cites W2038767330 @default.
• W3204251546 cites W2048645097 @default.
• W3204251546 cites W2049613058 @default.
• W3204251546 cites W2054759209 @default.
• W3204251546 cites W2056364460 @default.
• W3204251546 cites W2056930263 @default.
• W3204251546 cites W2067237008 @default.
• W3204251546 cites W2068709247 @default.
• W3204251546 cites W2069926129 @default.
• W3204251546 cites W2072933949 @default.
• W3204251546 cites W2081220317 @default.
• W3204251546 cites W2082235753 @default.
• W3204251546 cites W2084347031 @default.
• W3204251546 cites W2090747689 @default.
• W3204251546 cites W2092912053 @default.
• W3204251546 cites W2101542395 @default.
• W3204251546 cites W2105249240 @default.
• W3204251546 cites W2117288861 @default.
• W3204251546 cites W2119060556 @default.
• W3204251546 cites W2121657932 @default.
• W3204251546 cites W2166689829 @default.
• W3204251546 cites W2327599482 @default.
• W3204251546 cites W2407103127 @default.
• W3204251546 cites W2417607527 @default.
• W3204251546 cites W2547454912 @default.
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• W3204251546 cites W2585856814 @default.
• W3204251546 cites W2601337927 @default.
• W3204251546 cites W2604219113 @default.
• W3204251546 cites W2605795610 @default.
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• W3204251546 cites W2791799367 @default.
• W3204251546 cites W2906046709 @default.
• W3204251546 cites W2909685932 @default.
• W3204251546 cites W2923541034 @default.
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• W3204251546 doi "https://doi.org/10.1016/j.jics.2021.100182" @default.
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