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- W3204252954 abstract "The thermodynamic potential of the Pb x Sr 1-x TiO 3 solid solutions has been determined for the entire range of component concentrations. A phase diagram has been constructed, which contains: a critical point at which the line of second-order phase transitions passes into the line of first-order transitions between the cubic and tetragonal phases; a tricritical point at which the cubic, tetragonal, and rhombohedral phases converge; the multicritical point at which at low temperatures six phases converge along the lines of second-order transitions. The obtained T-x phase diagram of Pb x Sr 1-x TiO 3 shows the possibility of the existence of ferroelectric phases that were not previously observed in experiments. • The thermodynamic potential of Pb x Sr 1-x TiO 3 has been determined. • The T-x phase diagram of solid solutions of strontium-lead titanates is modeled. • New ferroelectric phases are found in the low temperature region." @default.
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- W3204252954 date "2022-02-01" @default.
- W3204252954 modified "2023-10-12" @default.
- W3204252954 title "Thermodynamic theory of PbxSr1-xTiO3 solid solutions" @default.
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- W3204252954 doi "https://doi.org/10.1016/j.jpcs.2021.110395" @default.
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