FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204279287> ?p ?o ?g. }

• W3204279287 abstract "Abstract In this article, new insights about the metals-porphyrin complexes are proved by analyzing the zinc, nickel and chromium adsorption process over the well-known porphyrin macromolecule. The use of the quartz crystal microbalance (QCM) apparatus allows the control of the complexation systems’ experimental adsorption data operating at four temperatures. The experimental results and the physical models reveal that the zinc and nickel complexation processes are to be examined using the mono layer adsorption model. While, the double layer model describes the interaction between the chromium compound and the porphyrin. Actually, the three metals are shown to be adsorbed by a multi-docking process in the physicochemical description. The endothermic character of the investigated processes is shown through the appropriate data of the principal parameter adsorbent sites’ density. Hence, several porphyrin sites are exclusively stimulated at high temperature. The parameters of van del Waals, depicting the influences of the lateral interactions, explain the nickel isotherms down trend. The chemical bonds are shown to be carried out between the zinc and the porphyrin through the calculated adsorption energies. Considering the thermodynamic study, and referring to the configurational entropy and the free enthalpy, it is to be noted that the disorder peak of the three mechanisms is reached when the equilibrium concentration is equal to the energetic parameters’ values for each system. The nickel enthalpy revealed for high concentration that the adsorbates’ lateral interactions disapproved the nickel chloride adsorption. The free enthalpy trends, that observed two stability states of the chromium compound, confirmed the chromium double layer mechanism." @default.
• W3204279287 created "2021-10-11" @default.
• W3204279287 creator A5009044356 @default.
• W3204279287 creator A5032787310 @default.
• W3204279287 creator A5047434973 @default.
• W3204279287 creator A5082826996 @default.
• W3204279287 date "2021-10-08" @default.
• W3204279287 modified "2023-10-16" @default.
• W3204279287 title "Interpretation of the adsorption of metals on quartz crystal based-macromolecule via advanced modeling of equilibrium isotherms" @default.
• W3204279287 cites W1964106942 @default.
• W3204279287 cites W1976866228 @default.
• W3204279287 cites W1978030516 @default.
• W3204279287 cites W1986113254 @default.
• W3204279287 cites W1988159655 @default.
• W3204279287 cites W1992593166 @default.
• W3204279287 cites W1992778528 @default.
• W3204279287 cites W1995157209 @default.
• W3204279287 cites W1995764503 @default.
• W3204279287 cites W2000186316 @default.
• W3204279287 cites W2000725842 @default.
• W3204279287 cites W2001736369 @default.
• W3204279287 cites W2003159852 @default.
• W3204279287 cites W2003794442 @default.
• W3204279287 cites W2017516584 @default.
• W3204279287 cites W2022578476 @default.
• W3204279287 cites W2024072561 @default.
• W3204279287 cites W2031074728 @default.
• W3204279287 cites W2034246534 @default.
• W3204279287 cites W2036348623 @default.
• W3204279287 cites W2038037324 @default.
• W3204279287 cites W2038809650 @default.
• W3204279287 cites W2041395768 @default.
• W3204279287 cites W2044955988 @default.
• W3204279287 cites W2045145644 @default.
• W3204279287 cites W2046326238 @default.
• W3204279287 cites W2061640733 @default.
• W3204279287 cites W2068862715 @default.
• W3204279287 cites W2069867186 @default.
• W3204279287 cites W2074322783 @default.
• W3204279287 cites W2080678112 @default.
• W3204279287 cites W2087070363 @default.
• W3204279287 cites W2090129581 @default.
• W3204279287 cites W2091115509 @default.
• W3204279287 cites W2092345069 @default.
• W3204279287 cites W2093708029 @default.
• W3204279287 cites W2094942169 @default.
• W3204279287 cites W2101760608 @default.
• W3204279287 cites W2107954542 @default.
• W3204279287 cites W2164998541 @default.
• W3204279287 cites W2331212077 @default.
• W3204279287 cites W2473212471 @default.
• W3204279287 cites W2599199563 @default.
• W3204279287 cites W2766023610 @default.
• W3204279287 cites W2772576298 @default.
• W3204279287 cites W2792065695 @default.
• W3204279287 cites W2803011689 @default.
• W3204279287 cites W2885109017 @default.
• W3204279287 cites W2904788895 @default.
• W3204279287 cites W2952447035 @default.
• W3204279287 cites W2967819526 @default.
• W3204279287 cites W2970031673 @default.
• W3204279287 cites W3031803491 @default.
• W3204279287 cites W3033824896 @default.
• W3204279287 cites W3095317752 @default.
• W3204279287 cites W3132109223 @default.
• W3204279287 doi "https://doi.org/10.1038/s41598-021-99465-9" @default.
• W3204279287 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8501105" @default.
• W3204279287 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34625608" @default.
• W3204279287 hasPublicationYear "2021" @default.
• W3204279287 type Work @default.
• W3204279287 sameAs 3204279287 @default.
• W3204279287 citedByCount "1" @default.
• W3204279287 countsByYear W32042792872022 @default.
• W3204279287 crossrefType "journal-article" @default.
• W3204279287 hasAuthorship W3204279287A5009044356 @default.
• W3204279287 hasAuthorship W3204279287A5032787310 @default.
• W3204279287 hasAuthorship W3204279287A5047434973 @default.
• W3204279287 hasAuthorship W3204279287A5082826996 @default.
• W3204279287 hasBestOaLocation W32042792871 @default.
• W3204279287 hasConcept C121332964 @default.
• W3204279287 hasConcept C126061179 @default.
• W3204279287 hasConcept C147789679 @default.
• W3204279287 hasConcept C150394285 @default.
• W3204279287 hasConcept C178790620 @default.
• W3204279287 hasConcept C179104552 @default.
• W3204279287 hasConcept C185592680 @default.
• W3204279287 hasConcept C204389451 @default.
• W3204279287 hasConcept C2779480358 @default.
• W3204279287 hasConcept C3288061 @default.
• W3204279287 hasConcept C32909587 @default.
• W3204279287 hasConcept C504270822 @default.
• W3204279287 hasConcept C511782168 @default.
• W3204279287 hasConcept C535196362 @default.
• W3204279287 hasConcept C55493867 @default.
• W3204279287 hasConcept C97355855 @default.
• W3204279287 hasConcept C9996572 @default.
• W3204279287 hasConceptScore W3204279287C121332964 @default.
• W3204279287 hasConceptScore W3204279287C126061179 @default.
• W3204279287 hasConceptScore W3204279287C147789679 @default.
• W3204279287 hasConceptScore W3204279287C150394285 @default.

• next