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• W3204285574 abstract "A luminescence sensor based on an europium(III)-based lanthanide-organic framework, [Eu(BCB)(DMF)]·(DMF)1.5(H2O)2 (1), was synthesized via a solvothermal method using 4,4',4''-benzenetricarbonyltribenzoic acid (H3BCB) as a bridging ligand. Single-crystal X-ray diffraction indicates that Eu centers are eight-coordinated with a trigonal dodecahedron and a square antiprismatic configuration, and adjacent Eu atoms are bridged by BCB organic linkers to form a 3D rod-packing structure. Photoluminescence studies show that compound 1 emits bright red luminescence and behaves as a multi-responsive luminescent sensor toward 4-nitrophenol (4-NP) and I- and Fe3+ ions in water with high sensitivity, selectivity and low detection limits. Furthermore, the possible luminescence sensing mechanisms were also investigated by PXRD analysis, UV-vis spectroscopy and X-ray photoelectron spectroscopy (XPS). The recognition mechanism for 4-NP and I- ions can be attributed to the competition absorption and that for Fe3+ ions is considered to be a multi-quenching mechanism dominated by competition absorption. This study demonstrates that the lanthanide-based MOF might be a promising candidate for the detection of 4-NP and I- and Fe3+ ions in aqueous medium." @default.
• W3204285574 created "2021-10-11" @default.
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• W3204285574 date "2021-01-01" @default.
• W3204285574 modified "2023-10-03" @default.
• W3204285574 title "An europium(<scp>iii</scp>) metal–organic framework as a multi-responsive luminescent sensor for highly sensitive and selective detection of 4-nitrophenol and I⁻ and Fe³⁺ ions in water" @default.
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• W3204285574 doi "https://doi.org/10.1039/d1dt02312h" @default.
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