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- W3204307530 abstract "Abstract Herein, the thiol‐yne photoclick reaction was utilized as a method for synthesizing imidazolium‐containing ionene networks whereby a bisalkynyl‐functionalized imidazolium [NTf 2 ] ionic liquid was polymerized with the tetrafunctional thiol PTMP (pentaerythritol tetrakis(3‐mercaptopropionate)). The thiol:yne functional group ratio was varied in order to examine the breadth of thermal, mechanical, and conductive properties available from the resulting networks. The stoichiometric 1:1 thiol:yne network exhibited very high thiol and alkyne conversions by FT‐IR spectroscopy and a gel fraction greater than 95%. The highest T g value (3.5°C) and stress at break (1.13 MPa) were also observed for this network. As either thiol or alkyne functional group concentration was increased, the networks were noticeably lower in T g and stress at break with a modest increase in % elongation. Ionic conductivities were found to be on the order of 10 −9 to 10 −7 S/cm at 30°C. Normalization of the ionic conductivity curves did not lead to a complete collapse meaning that the observed differences in conductivity are not solely dependent upon T g . When compared to analogous imidazolium‐containing, thiol‐ene ionene networks, the thiol‐yne networks were found to be slightly more mechanically robust, but approximately one order of magnitude lower in terms of ionic conductivity." @default.
- W3204307530 created "2021-10-11" @default.
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- W3204307530 date "2021-10-01" @default.
- W3204307530 modified "2023-10-13" @default.
- W3204307530 title "Thiol‐yne photoclick polymerization as a method for preparing <scp>imidazolium‐containing</scp> ionene networks" @default.
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- W3204307530 doi "https://doi.org/10.1002/pol.20210629" @default.
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