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- W3204324237 abstract "Upon the irradiation, photocatalyst such as TiO2, produces electrons and positive holes on the particle surface. The positive hole reacts with hydroxide on the TiO2 surface to form hydroxyl radicals which can oxidize organic compounds such as chlorinated phenols to Cl- and CO2 in the presence of oxygen. Oxygen plays an important role in trapping electrons on the TiO2 surface and inhibiting electron/hole recombination. Depending upon the degree of chlorination the decomposition rate decreases in the order: monochlorophenol > dichlorophenol > trichlorophenol. With the same degree of chlorination, the Cl atom at para-position tend to be replaced easily by OH radical. Therefore the decomposition rate increases in order: 4CP > 3CP >2CP for monochlorophenols and 26DCP = 25DCP > 34DCP = 24DCP > 23DCP for dichlorophenols. Symmetrical nature of chlorophenols and their intermediates facilitates attack by OH radical due to a favorable orientation. Low yield of carbon dioxide and chloride indicated that photolytic process can not convert chlorophenol into mineral acids." @default.
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- W3204324237 date "2021-05-30" @default.
- W3204324237 modified "2023-09-23" @default.
- W3204324237 title "Photocatalytic Oxidation Process for the Treatment of Organic Wastes" @default.
- W3204324237 doi "https://doi.org/10.1201/9781003210597-21" @default.
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