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• W3204331973 abstract "The electronic spectroscopy and photophysics of 1,2-benzazulene (BzAz) have been examined in solution and in thin solid films, with the objective of comparing its intramolecular and intermolecular excited state decay processes with those of azulene. Unlike azulene, the S2 – S0 absorption and fluorescence spectra exhibit a clear mirror image relationship dominated by a single strong Franck-Condon active progression. Picosecond transient absorption spectra and non-linear S2 fluorescence upconversion experiments reveal lifetimes that follow a well-established energy gap law correlation, indicative of a dominant S2 – S1 decay route. Mechanistic interpretations, including the possibility of S2 singlet fission in aggregates, are discussed." @default.
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• W3204331973 date "2021-12-01" @default.
• W3204331973 modified "2023-10-18" @default.
• W3204331973 title "Photophysics and spectroscopy of 1,2-Benzazulene" @default.
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• W3204331973 doi "https://doi.org/10.1016/j.cplett.2021.139114" @default.
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