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• W3204337960 endingPage "2486" @default.
• W3204337960 startingPage "2429" @default.
• W3204337960 abstract "Alkoxy radicals are highly reactive species that have long been recognized as versatile intermediates in organic synthesis. However, their development has long been impeded due to a lack of convenient methods for their generation. Thanks to advances in photoredox catalysis, enabling facile access to alkoxy radicals from bench-stable precursors and free alcohols under mild conditions, research interest in this field has been renewed. This review comprehensively summarizes the recent progress in alkoxy radical-mediated transformations under visible light irradiation. Elementary steps for alkoxy radical generation from either radical precursors or free alcohols are central to reaction development; thus, each section is categorized and discussed accordingly. Throughout this review, we have focused on the different mechanisms of alkoxy radical generation as well as their impact on synthetic utilizations. Notably, the catalytic generation of alkoxy radicals from abundant alcohols is still in the early stage, providing intriguing opportunities to exploit alkoxy radicals for diverse synthetic paradigms." @default.
• W3204337960 created "2021-10-11" @default.
• W3204337960 creator A5011741304 @default.
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• W3204337960 creator A5044732414 @default.
• W3204337960 creator A5073968585 @default.
• W3204337960 creator A5076125491 @default.
• W3204337960 date "2021-10-06" @default.
• W3204337960 modified "2023-10-16" @default.
• W3204337960 title "Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis" @default.
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