FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204349270> ?p ?o ?g. }

• W3204349270 endingPage "151343" @default.
• W3204349270 startingPage "151343" @default.
• W3204349270 abstract "The precise control of the selectivity of intermediates in nitrobenzene reduction is a time-honored challenge. Herein, we report a regulatory method for improving the selectivity of azoxybenzene using four rationally tailored CeO2 catalysts, whose exposed planes, acid–base chemistries, and defect properties in terms of Ce3+ cations and O-vacancies are optimized. Among the four catalysts, Spindle-structured CeO2, which has the largest concentration of Ce3+ cations and O-vacancy defects exhibits the highest nitrobenzene conversion rate. However, it exhibits a lower azoxybenzene selectivity (70.5%) than Rod-CeO2 (90.4%). Based on the semi-quantitative characterization results and the initial rates of the rate-determining step, the defect densities of the CeO2 catalysts are demonstrated to correspond to their catalytic selectivity. Density functional theory (DFT) calculations and in situ capping tests further reveal that the parent Ce3+ cations of O-vacancy defects serve as adsorption-activation sites for nitro groups of nitrobenzene. Moreover, the O-vacancy defects serve as the main active sites and conduce the over-reduction of azoxybenzene, which should be inhibited to improve the azoxybenzene selectivity. Therefore, regulating the O-vacancy defects at the moderate concentration is responsible for the satisfactory azoxybenzene yield of 90.4% exhibited by Rod-CeO2 nanocrystals." @default.
• W3204349270 created "2021-10-11" @default.
• W3204349270 creator A5013117145 @default.
• W3204349270 creator A5038425593 @default.
• W3204349270 creator A5049281967 @default.
• W3204349270 creator A5049692788 @default.
• W3204349270 creator A5051935973 @default.
• W3204349270 creator A5062883545 @default.
• W3204349270 creator A5090395315 @default.
• W3204349270 date "2022-01-01" @default.
• W3204349270 modified "2023-10-14" @default.
• W3204349270 title "Enhancing nitrobenzene reduction to azoxybenzene by regulating the O-vacancy defects over rationally tailored CeO2 nanocrystals" @default.
• W3204349270 cites W1781627120 @default.
• W3204349270 cites W1886706438 @default.
• W3204349270 cites W1929977450 @default.
• W3204349270 cites W1970127494 @default.
• W3204349270 cites W1981368803 @default.
• W3204349270 cites W1988866685 @default.
• W3204349270 cites W1999018554 @default.
• W3204349270 cites W2000289532 @default.
• W3204349270 cites W2007163007 @default.
• W3204349270 cites W2007395042 @default.
• W3204349270 cites W2011404653 @default.
• W3204349270 cites W2020830441 @default.
• W3204349270 cites W2021287104 @default.
• W3204349270 cites W2022081701 @default.
• W3204349270 cites W2029728117 @default.
• W3204349270 cites W2049047312 @default.
• W3204349270 cites W2049248516 @default.
• W3204349270 cites W2059411852 @default.
• W3204349270 cites W2065477664 @default.
• W3204349270 cites W2067077957 @default.
• W3204349270 cites W2077859214 @default.
• W3204349270 cites W2080111592 @default.
• W3204349270 cites W2080144138 @default.
• W3204349270 cites W2083205829 @default.
• W3204349270 cites W2083222334 @default.
• W3204349270 cites W2109020335 @default.
• W3204349270 cites W2136760958 @default.
• W3204349270 cites W2140906782 @default.
• W3204349270 cites W2146024685 @default.
• W3204349270 cites W2147786485 @default.
• W3204349270 cites W2166319170 @default.
• W3204349270 cites W2230728100 @default.
• W3204349270 cites W2325852722 @default.
• W3204349270 cites W2326949162 @default.
• W3204349270 cites W267527631 @default.
• W3204349270 cites W2751540264 @default.
• W3204349270 cites W2890065603 @default.
• W3204349270 cites W2902653608 @default.
• W3204349270 cites W2994039657 @default.
• W3204349270 doi "https://doi.org/10.1016/j.apsusc.2021.151343" @default.
• W3204349270 hasPublicationYear "2022" @default.
• W3204349270 type Work @default.
• W3204349270 sameAs 3204349270 @default.
• W3204349270 citedByCount "9" @default.
• W3204349270 countsByYear W32043492702022 @default.
• W3204349270 countsByYear W32043492702023 @default.
• W3204349270 crossrefType "journal-article" @default.
• W3204349270 hasAuthorship W3204349270A5013117145 @default.
• W3204349270 hasAuthorship W3204349270A5038425593 @default.
• W3204349270 hasAuthorship W3204349270A5049281967 @default.
• W3204349270 hasAuthorship W3204349270A5049692788 @default.
• W3204349270 hasAuthorship W3204349270A5051935973 @default.
• W3204349270 hasAuthorship W3204349270A5062883545 @default.
• W3204349270 hasAuthorship W3204349270A5090395315 @default.
• W3204349270 hasConcept C114221277 @default.
• W3204349270 hasConcept C118792377 @default.
• W3204349270 hasConcept C147597530 @default.
• W3204349270 hasConcept C147789679 @default.
• W3204349270 hasConcept C150394285 @default.
• W3204349270 hasConcept C152365726 @default.
• W3204349270 hasConcept C161790260 @default.
• W3204349270 hasConcept C171250308 @default.
• W3204349270 hasConcept C175854130 @default.
• W3204349270 hasConcept C178790620 @default.
• W3204349270 hasConcept C179104552 @default.
• W3204349270 hasConcept C185592680 @default.
• W3204349270 hasConcept C192562407 @default.
• W3204349270 hasConcept C2780809723 @default.
• W3204349270 hasConcept C75473681 @default.
• W3204349270 hasConcept C8010536 @default.
• W3204349270 hasConceptScore W3204349270C114221277 @default.
• W3204349270 hasConceptScore W3204349270C118792377 @default.
• W3204349270 hasConceptScore W3204349270C147597530 @default.
• W3204349270 hasConceptScore W3204349270C147789679 @default.
• W3204349270 hasConceptScore W3204349270C150394285 @default.
• W3204349270 hasConceptScore W3204349270C152365726 @default.
• W3204349270 hasConceptScore W3204349270C161790260 @default.
• W3204349270 hasConceptScore W3204349270C171250308 @default.
• W3204349270 hasConceptScore W3204349270C175854130 @default.
• W3204349270 hasConceptScore W3204349270C178790620 @default.
• W3204349270 hasConceptScore W3204349270C179104552 @default.
• W3204349270 hasConceptScore W3204349270C185592680 @default.
• W3204349270 hasConceptScore W3204349270C192562407 @default.
• W3204349270 hasConceptScore W3204349270C2780809723 @default.
• W3204349270 hasConceptScore W3204349270C75473681 @default.
• W3204349270 hasConceptScore W3204349270C8010536 @default.

• next