Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204353896> ?p ?o ?g. }
- W3204353896 endingPage "25728" @default.
- W3204353896 startingPage "25723" @default.
- W3204353896 abstract "The development of a straightforward strategy to obtain enantioenriched silicon-stereogenic benzosiloles remains a challenging yet appealing synthesis venture due to their potential future application in chiral electronic and optoelectronic devices. In this context, all of the existing methods rely on Rh-catalyzed systems and are somewhat limited in scope. Herein, we disclose the first Ni0 -catalyzed ring expansion process that enables the preparation of benzosiloles possessing tetraorganosilicon stereocenters in excellent yields and enantioselectivities. The presented catalysis strategy is further applied to the asymmetric synthesis of silicon-stereogenic bis-silicon-bridged π-extended systems. Preliminary studies reveal that such compounds exhibit fluorescence emission, Cotton effects and circularly polarized luminescence (CPL) activity." @default.
- W3204353896 created "2021-10-11" @default.
- W3204353896 creator A5025372898 @default.
- W3204353896 creator A5061416011 @default.
- W3204353896 creator A5071019275 @default.
- W3204353896 creator A5072422702 @default.
- W3204353896 date "2021-11-02" @default.
- W3204353896 modified "2023-10-05" @default.
- W3204353896 title "Nickel(0)‐Catalyzed Asymmetric Ring Expansion Toward Enantioenriched Silicon‐Stereogenic Benzosiloles" @default.
- W3204353896 cites W1129356412 @default.
- W3204353896 cites W1797418650 @default.
- W3204353896 cites W1964387880 @default.
- W3204353896 cites W1985896551 @default.
- W3204353896 cites W1995740258 @default.
- W3204353896 cites W1997861523 @default.
- W3204353896 cites W1997937043 @default.
- W3204353896 cites W2014661935 @default.
- W3204353896 cites W2016640798 @default.
- W3204353896 cites W2032510498 @default.
- W3204353896 cites W2036501021 @default.
- W3204353896 cites W2039017242 @default.
- W3204353896 cites W2051695125 @default.
- W3204353896 cites W2052150506 @default.
- W3204353896 cites W2058240611 @default.
- W3204353896 cites W2059293485 @default.
- W3204353896 cites W2064890648 @default.
- W3204353896 cites W2079267277 @default.
- W3204353896 cites W2081668568 @default.
- W3204353896 cites W2091844487 @default.
- W3204353896 cites W2096573295 @default.
- W3204353896 cites W2109948016 @default.
- W3204353896 cites W2119303897 @default.
- W3204353896 cites W2122320720 @default.
- W3204353896 cites W2127181275 @default.
- W3204353896 cites W2128284659 @default.
- W3204353896 cites W2137435380 @default.
- W3204353896 cites W2147650774 @default.
- W3204353896 cites W2156731801 @default.
- W3204353896 cites W2160360943 @default.
- W3204353896 cites W2167166532 @default.
- W3204353896 cites W2277959218 @default.
- W3204353896 cites W2315133004 @default.
- W3204353896 cites W2325178155 @default.
- W3204353896 cites W2330013525 @default.
- W3204353896 cites W2415204380 @default.
- W3204353896 cites W2441456267 @default.
- W3204353896 cites W2461979184 @default.
- W3204353896 cites W2523396758 @default.
- W3204353896 cites W2563663854 @default.
- W3204353896 cites W2612859807 @default.
- W3204353896 cites W2757422022 @default.
- W3204353896 cites W2770222964 @default.
- W3204353896 cites W2790011620 @default.
- W3204353896 cites W2811419479 @default.
- W3204353896 cites W2847530093 @default.
- W3204353896 cites W2900221282 @default.
- W3204353896 cites W2914960554 @default.
- W3204353896 cites W2921485378 @default.
- W3204353896 cites W2925737876 @default.
- W3204353896 cites W2949149615 @default.
- W3204353896 cites W2949590256 @default.
- W3204353896 cites W2951617678 @default.
- W3204353896 cites W2952078715 @default.
- W3204353896 cites W2953124768 @default.
- W3204353896 cites W2957536126 @default.
- W3204353896 cites W2970784242 @default.
- W3204353896 cites W2983394608 @default.
- W3204353896 cites W3001766022 @default.
- W3204353896 cites W3005434703 @default.
- W3204353896 cites W3009346209 @default.
- W3204353896 cites W3034696044 @default.
- W3204353896 cites W3035475166 @default.
- W3204353896 cites W3104008064 @default.
- W3204353896 cites W3111104076 @default.
- W3204353896 cites W3126337092 @default.
- W3204353896 cites W3145850771 @default.
- W3204353896 cites W3147930844 @default.
- W3204353896 cites W3180058048 @default.
- W3204353896 cites W415195649 @default.
- W3204353896 cites W4231346390 @default.
- W3204353896 cites W4237754141 @default.
- W3204353896 cites W4242495195 @default.
- W3204353896 cites W4244072933 @default.
- W3204353896 cites W4250516084 @default.
- W3204353896 cites W4256599989 @default.
- W3204353896 cites W4361865858 @default.
- W3204353896 doi "https://doi.org/10.1002/anie.202111025" @default.
- W3204353896 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34590411" @default.
- W3204353896 hasPublicationYear "2021" @default.
- W3204353896 type Work @default.
- W3204353896 sameAs 3204353896 @default.
- W3204353896 citedByCount "38" @default.
- W3204353896 countsByYear W32043538962022 @default.
- W3204353896 countsByYear W32043538962023 @default.
- W3204353896 crossrefType "journal-article" @default.
- W3204353896 hasAuthorship W3204353896A5025372898 @default.
- W3204353896 hasAuthorship W3204353896A5061416011 @default.
- W3204353896 hasAuthorship W3204353896A5071019275 @default.