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• W3204366830 abstract "A visible-light-driven photoredox-catalyzed nonaqueous oxidative C-N cleavage of N,N-dibenzylanilines to 2° amides is reported. Further, we have applied this protocol on 2-(dibenzylamino)benzamide to afford quinazolinones with (NH4)2S2O8 as an additive. Mechanistic studies imply that the reaction might undergo in situ generation of α-amino radical to imine by C-N bond cleavage followed by the addition of superoxide ion to form amides." @default.
• W3204366830 created "2021-10-11" @default.
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• W3204366830 date "2021-10-08" @default.
• W3204366830 modified "2023-09-30" @default.
• W3204366830 title "Regioselective Synthesis of 2° Amides Using Visible-Light-Induced Photoredox-Catalyzed Nonaqueous Oxidative C–N Cleavage of <i>N</i>,<i>N</i>-Dibenzylanilines" @default.
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• W3204366830 doi "https://doi.org/10.1021/acs.joc.1c01792" @default.
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